306970-84-3Relevant academic research and scientific papers
Ni(II)-piperidinedithiocarbamate complexes with bidentate phosphorus-donor ligands
Pastorek, Richard,Trávní?ek, Zdeněk,Marek, Jaromír,Dastych, Dalibor,?indelá?, Zdeněk
, p. 1713 - 1717 (2000)
Nickel(II) piperidinedithiocarbamate complexes of the composition [Ni(pipdtc)(P-P)]X and [Ni2(pipdtc)2(NCS)2(dpph)] (X = NCS, ClO4, I; P-P = 1,2-bis(diphenylphosphino)ethane (dppe), 1,4-bis(diphenylphosphino)butane (dppb), 1,6-bis(diphenylphosphino)hexane (dpph), 1,4-bis(diphenylphosphino)ferrocene (dppf); pip=C5H10; dtc=S2CN-) have been synthesized. The compounds have been characterized by elemental analyses, IR, electron and 1H, 13C{1H} and 31P{1H} NMR spectroscopies, thermal analysis, magneto-chemical and conductivity measurements. A single-crystal X-ray analysis of the [Ni(pipdtc)(dppf)]ClO4 complex proved four-coordinated nickel in a deformed square-planar arrangement with a S2P2 donor set. (C) 2000 Elsevier Science Ltd.
