306973-75-1

Basic information

• Product Name: (1S,2S,5R)-2-i-propyl-5-methyl-1-[2-(2-furanyl)-1-ethyn-1-yl]cyclohexan-1-ol
• Synonyms: (1S,2S,5R)-2-i-propyl-5-methyl-1-[2-(2-furanyl)-1-ethyn-1-yl]cyclohexan-1-ol
• CAS NO: 306973-75-1
• Molecular Weight: 246.349
• Mol File: 306973-75-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1S,2S,5R)-2-i-propyl-5-methyl-1-[2-(2-furanyl)-1-ethyn-1-yl]cyclohexan-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,2S,5R)-2-i-propyl-5-methyl-1-[2-(2-furanyl)-1-ethyn-1-yl]cyclohexan-1-ol(306973-75-1)
• EPA Substance Registry System: (1S,2S,5R)-2-i-propyl-5-methyl-1-[2-(2-furanyl)-1-ethyn-1-yl]cyclohexan-1-ol(306973-75-1)

Safety Data

• Hazardous Substances Data: 306973-75-1(Hazardous Substances Data)

Upstream product

• 18649-64-4 2-ethynylfuran 
• 10458-14-7 (2R,5S)-menthone 

Relevant articles and documents

Chiral α-substituted carbonyls and alcohols from the S(N)2' displacement of cuprates on chiral carbonates: An alternative to the alkylation of chiral enolates

A highly stereoselective sequence of reactions, based on the anti-selective S(N)2' addition of cuprates to allylic carbonates, transforms alkynes or alkenyl halides into carbonyls having α-chiral centers. The method, which uses menthone as a chiral auxiliary, is a useful alternative to the alkylation of chiral enolates with the added advantage of allowing for the 'alkylation' of sec- and tert-alkyl and aryl groups.