30711-41-2Relevant articles and documents
Mono-ketone modified C60s for acceptor materials in organic photovoltaic cells
Lee, Hak Sung,Yoon, Sung Cheol,Lim, Jongsun,Lee, Myongsoo,Lee, Changjin
, p. 293 - 302 (2008)
We designed and synthesized methanofullerene derivatives with several types of thiophenyl mono-ketone for application in organic photovoltaic cells (OPVCs) as new accepter materials. The various mono-ketones having thiophene rings were substituted onto fullerene through application of Hirch-Bingel reaction under mild condition to compete with donor materials especially P3HT [Poly(3-hexylthiophene)] for nano-networking bulk-heterojunction structure where efficient light-induced charge separation is enable by a large-area donor-acceptor interface. The newly synthesized methanofullerene derivatives were characterized through 1H-NMR and FAB Mass spectroscopy. The compounds were also applied in OPV cell devices with P3HT as a donor material and measured electrochemical the property and power conversion efficiency.
Iron(III)-Catalyzed Hydration of Unactivated Internal Alkynes in Weak Acidic Medium, under Lewis Acid-Assisted Br?nsted Acid Catalysis
Antenucci, Achille,Flamini, Piergiorgio,Fornaiolo, Marco Valerio,Di Silvio, Sergio,Mazzetti, Sara,Mencarelli, Paolo,Salvio, Riccardo,Bassetti, Mauro
, p. 4517 - 4526 (2019/08/26)
Alkylarylalkynes are converted with full regioselectivity into the corresponding arylketones by formal hydration of the triple bond under weak acidic conditions, at times and temperatures (≤95 °C) comparable to those used for terminal alkynes. The process catalyzed by Fe2(SO4)3nH2O in glacial acetic acid exhibits good functional group compatibility, including that with bulky triple bond substituents, and can be extended to the one-pot transformation of aryltrimethylsilylacetylenes into acetyl derivatives via a desilylation-hydration sequence. The overall reactivity pattern along with proton affinity data indicate that the triple bond is activated by proton transfer rather than by π-interaction with the metal ion. This mechanistic feature, at variance with that of noble metal catalysts, accounts for the total regioselectivity and the insensitivity to steric hindrance exhibited by the Fe2(SO4)3nH2O/AcOH catalytic system. (Figure presented.).
New approach to the synthesis of 2,2':5',2''-terthiophene-5,5''-and 2,2':5',2'':5'',2'''-quaterthiophene-5,5'''-dicarboxylic acids
Kostyuchenko, Anastasia S.,Ulyankin, Evgeny B.,Shatsauskas, Anton L.,Shuvalov, Vladislav Yu.,Fisyuk, Alexander S.
, p. 1026 - 1032 (2019/01/04)
[Figure not available: see fulltext.] The reaction of bromosuccinimide with esters of 3-substituted 2,2'-bithiophene-5-carboxylic acids was used to obtain their 5'-bromo derivatives, which were further converted to esters of 3,3'''-disubstituted 2,2':5',2