308258-36-8

Basic information

• Product Name: Propionic acid 1-[2-((S)-2,2-dimethyl-6-methylene-cyclohexyl)-ethyl]-1-methyl-allyl ester
• Synonyms: Propionic acid 1-[2-((S)-2,2-dimethyl-6-methylene-cyclohexyl)-ethyl]-1-methyl-allyl ester
• CAS NO: 308258-36-8
• Molecular Weight: 278.435
• Mol File: 308258-36-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Propionic acid 1-[2-((S)-2,2-dimethyl-6-methylene-cyclohexyl)-ethyl]-1-methyl-allyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Propionic acid 1-[2-((S)-2,2-dimethyl-6-methylene-cyclohexyl)-ethyl]-1-methyl-allyl ester(308258-36-8)
• EPA Substance Registry System: Propionic acid 1-[2-((S)-2,2-dimethyl-6-methylene-cyclohexyl)-ethyl]-1-methyl-allyl ester(308258-36-8)

Safety Data

• Hazardous Substances Data: 308258-36-8(Hazardous Substances Data)

Upstream product

• 24190-33-8 (+)-(S)-dihydro-γ-ionone 
• 52690-42-3 (-)-4-<(1S,6R)-2,2,6-trimethyl-6-vinylcyclohexyl>butan-2-one 

Downstream Products

• 145398-73-8 luffarin-W 
• 308258-39-1 4-[(E)-1-Benzenesulfonyl-6-((S)-2,2-dimethyl-6-methylene-cyclohexyl)-4-methyl-hex-3-enyl]-5H-furan-2-one 

Relevant articles and documents

Synthetic applications of the thermal rearrangement of ozonides: First enantiospecific synthesis of marine metabolite Luffarin W

The ozonides on quaternary carbons undergo thermal rearrangement to yield a mixture of formates and alkenes. This reaction constitutes an alternative procedure to the unusual Baeyer-Villiger rearrangement of aliphatic aldehydes. The first enantiospecific synthesis of the marine metabolite Luffarin W from (-)-sclareol has been carried out, based on this methodology.