308258-39-1Relevant academic research and scientific papers
Synthetic applications of the thermal rearrangement of ozonides: First enantiospecific synthesis of marine metabolite Luffarin W
Barrero,Alvarez-Manzaneda,Chahboun,Cuerva,Segovia
, p. 1269 - 1272 (2007/10/03)
The ozonides on quaternary carbons undergo thermal rearrangement to yield a mixture of formates and alkenes. This reaction constitutes an alternative procedure to the unusual Baeyer-Villiger rearrangement of aliphatic aldehydes. The first enantiospecific synthesis of the marine metabolite Luffarin W from (-)-sclareol has been carried out, based on this methodology.
