308366-33-8

Upstream product

• 1212-08-4 S-Phenyl benzenethiosulfonate 
• 308366-28-1 (4Sp,13Rp)-4-bromo-13-(4,4-dimethyl-2-oxazolin-2-yl)[2.2]paracyclophane 
• 20586-49-6 [2.2]paracyclophane-4-carboxylic acid 
• 1633-22-3 [2.2]Paracyclophan 
• 1908-61-8 4-bromo[2.2]paracyclophane 
• 56439-07-7 pseudo-meta-bromo-<2.2>paracyclophane-4-carboxylic acid 
• 108869-37-0 [2.2]paracyclophane-4-carboxylic acid chloride 
• 308366-30-5 4-(4,4-dimethyloxazolin-2-yl)[2.2]paracyclophane 
• 308366-29-2 N-(1-hydroxy-2-methyl-2-propyl)[2.2]paracyclophane-13-carboxamide 
• 308366-27-0 (4Sp,13Rp)-4-bromo-N-(1-hydroxy-2-methylprop-2-yl)[2.2]paracyclophane-13-carboxamide 

Relevant academic research and scientific papers

The synthesis of homochiral ligands based on [2.2]paracyclophane

A new ortho-lithiation of homochiral 4-N,N-diethylamido[2.2]paracyclophane 8 is the key to the production of a wide variety of 4,5-disubstituted homochiral ligands. ψ-Geminal bromination of 8 proceeds in high yields and the resulting bromide may be conver

Oxazoline mediated routes to a unique amino-acid, 4-amino-13-carboxy[2.2]paracyclophane, of planar chirality

Efficient syntheses leading to 4-amino-13-carboxy[2.2]paracyclophane and derivatives are described. Novel oxazolinyl[2.2]paracyclophanes are used as intermediates and the oxazolinyl and amide groups are shown to be strong ψ-geminal directing groups. Compounds with potential as catalysts have been made. (C) 2000 Elsevier Science Ltd.