308804-94-6Relevant academic research and scientific papers
Solvent effect in the Wittig reaction under Boden's conditions
Pandolfi, Enrique M.,Lopez, Gloria V.,Dias, Eduardo,Seoane, Gustavo A.
, p. 2187 - 2196 (2003)
An interesting change in the stereochemical outcome of the Wittig olefination reaction under Boden's conditions (potassium bases and 18-crown-6 as the ylide forming reagent) is reported. This effect depends significantly on the polarity of the solvents an
Total synthesis of Marchantinquinone
Lopez,Pandolfi,Seoane
, p. 1403 - 1408 (2007/10/03)
The first synthesis of the title compound is described. Salient features include biaryl ether formation through S(N)Ar reactions and macrocyclization via a [Ni]0 mediated intramolecular coupling reaction.
