308832-46-4Relevant articles and documents
Generation of alkoxycarbenium ion pools from thioacetals and applications to glycosylation chemistry
Suzuki, Shinkiti,Matsumoto, Kouichi,Kawamura, Kohsuke,Suga, Seiji,Yoshida, Jun-Ichi
, p. 3755 - 3758 (2004)
(Chemical Equation Presented) Alkoxycarbenium ions have been generated and accumulated as "cation pools" by the low-temperature electrochemical oxidation of α-phenylthioethers. Although an unsuccessful attempt to accumulate glycosyl cations was made, a one-pot method for electrochemical glycosylation, which involves anodic oxidation of thioglycosides to generate glycosyl cation equivalents followed by their reactions with glycosyl acceptors, has been developed.
