99054-47-4

Basic information

• Product Name: Benzene, [(1-methoxynonyl)thio]-
• CAS NO: 99054-47-4
• Molecular Formula: C16H26OS
• Molecular Weight: 266.448
• Mol File: 99054-47-4.mol

Chemical Properties

• CAS DataBase Reference: Benzene, [(1-methoxynonyl)thio]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(1-methoxynonyl)thio]-(99054-47-4)
• EPA Substance Registry System: Benzene, [(1-methoxynonyl)thio]-(99054-47-4)

Safety Data

• Hazardous Substances Data: 99054-47-4(Hazardous Substances Data)

Upstream product

• 124-19-6 nonan-1-al 
• 17314-33-9 tributyltin phenyl sulfide 
• 18824-63-0 1,1-dimethoxynonane 
• 108-98-5 thiophenol 
• 13865-50-4 methoxymethyl phenyl sulfide 
• 14365-16-3 bis-(phenylthio)-dibutylstannane 
• 4551-15-9 phenylthiotrimethylsilane 
• 67-56-1 methanol 
• 75340-08-8 1-phenylthio-1-trimethylsilylnonane 

Downstream Products

• 1103584-36-6 4-octyl-2,3-diphenylthiochroman 
• 13133-62-5 thiophenolate 
• 308832-46-4 Methyl-non-(E)-ylidene-oxonium 
• 116204-95-6 4-Methoxy-dodec-1-yne 
• 116204-96-7 (1-Prop-2-ynyl-nonylsulfanyl)-benzene 
• 116204-94-5 [1-(2-Methyl-allyl)-nonylsulfanyl]-benzene 
• 116204-91-2 4-methoxy-dodec-1-ene 
• 116204-92-3 (1-Allyl-nonylsulfanyl)-benzene 

Relevant articles and documents

Trimethylsilyl Trifluoromethanesulfonate Promoted Chemoselective Reactions of Acyclic Acetals in the Presence of Cyclic Acetals

Trimethylsilyl trifluoromethanesulfonate promoted chemoselective reactions of acyclic acetals with allyltrimethylsilane, allyltributyltin, a silyl enol ether, tributyltin hydride, trimethylsilyl azide and trimethylsilyl cyanide have been achieved in the p

ACTIVATION AND SYNTHETIC APPLICATIONS OF THIOSTANNANES. THIOALKOXYLATION OF ACETALS

The Sn-S bonds in thiostannanes, BunSn(SPh)4-n, are activated towards acetals in the presence of BF3*OEt2.Acetals of various aldehydes and ketones are converted into the corresponding monothioacetals under mild conditions.Employment of α-enal acetals induces Michael addition to give synthetically useful γ-alkoxyally sulfides.

METHOXY(PHENYLTHIO)METHANE AS AN AMBI-EQUVIVALENT OF A METHOXY- OR PHENYLTHIOMETHYLENE 1,1-DIPOLE

Methoxy(phenylthio)methane undergoes electrophilic alkylation followed by nucleophilic allylation or propargylation which is dramatically changed depending on the Lewis acid employed providing a methoxy- or phenylthiomethylene 1,1-dipole synthon.

Organotin-Mediated Preparation of Monothioacetals

Monothioacetals are obtained by treating the corresponding acetals with organotin thiophenoxides in the presence of BF3*OEt2.The reaction proceeds under mild conditions to provide the desired compounds with high selectivity.

Electrochemical Oxidation of 1-Phenylthio-1-trimethylsilylalkanes

Electrochemical oxidation of 1-phenylthio-1-trimethylsilylalkanes in the presence of alcohol resulted in facile cleavage of the carbon-silicon bond and formation of the corresponding acetals.