308848-71-7Relevant articles and documents
Titanocene-catalyzed metallation of propargylic acetates in homopropargyl alcohol synthesis
Meloche, Jennifer L.,Vednor, Peter T.,Gianino, Joseph B.,Oliver, Allen G.,Ashfeld, Brandon L.
supporting information, p. 5025 - 5028 (2015/01/09)
The titanium-catalyzed metallation and subsequent carbonyl addition of propargylic acetates enable the direct formation of homopropargylic alcohols in good yields. The corresponding products were obtained as single regioisomers without the corresponding a
TiCl4-mediated nucleophilic substitution of propargylic esters
Mahrwald,Quint
, p. 7463 - 7468 (2007/10/03)
Direct displacement reactions of propargylic esters are reported. 10 mol% of TiCl4 were used to carry out a nucleophilic substitution. Scope and limitation of this novel reaction are described. (C) 2000 Elsevier Science Ltd.