3094-85-7Relevant academic research and scientific papers
Binding multidentate ligands to Ni2+: Kinetic identification of preferential binding sites
Nartop, Dilek,Clegg, William,Harrington, Ross W.,Henderson, Richard A.,Wills, Corinne Y.
, p. 3372 - 3382 (2014/03/21)
The kinetics of the reactions between [Ni(MeOH)6]2+ (hereafter Ni2+) and a variety of neutral Schiff base multidentate ligands have been measured in methanol at 25.0°C using stopped-flow spectrophotometry. The ligands cont
Rhenium(I), (III) and (V) complexes of tridentate ONX (X = O, N, S)-donor Schiff bases
Mayer,Potgieter,Gerber
experimental part, p. 1423 - 1430 (2010/05/01)
The reactions of the potentially tridentate Schiff bases 2-[(2-hydroxyphenyl)iminomethyl]phenol (H2ono) and 2-(2-aminobenzylideneimino)phenol (H3onn) with trans-[ReOBr3(PPh3)2] were studied, and the complexes [ReIIIBr(PPh3)2(ono)] (1) and [ReVBr(PPh3)2(onn)]Br (2) were isolated. In 1 ono acts as a dianionic tridentate ligand, and in 2 onn is coordinated as a tridentate trianionic imido-imino-phenolate. The complex [ReI(CO)3(ons)(Hno)] was isolated from the reaction of [Re(CO)5Br] with 2-[(2-methylthio)benzylideneimino]phenol (Hons; Hno = 2-aminophenol), with ons coordinated as a bidentate chelate with a free SCH3 group. These complexes were characterized by X-ray crystallography, NMR and IR spectroscopy.
