3095-34-9Relevant academic research and scientific papers
C-P bond-forming reactions via C-O/P-h cross-coupling catalyzed by nickel
Yang, Jia,Chen, Tieqiao,Han, Li-Biao
, p. 1782 - 1785 (2015)
The first Ni-catalyzed C-O/P-H cross-coupling producing organophosphorus compounds is disclosed. This method features wide generality in regard to both C-O and P-H compounds: for C-O compounds, the readily available alcohol derivatives of aryl, alkenyl, benzyl, and allyl are applicable, and for P-H compounds, both >PV(O)H compounds (secondary phosphine oxide, H-phosphinate, and H-phosphonate) and hydrogen phosphines (>PIIIH) can be used as the substrates. Thus, a variety of valuable C(sp2)-P and C(sp3)-P compounds can be readily obtained in good to excellent yields by this new strategy.
