3101-50-6Relevant academic research and scientific papers
METHYLENATION OF CARBONYL COMPOUNDS WITH METHYLENEDIMAGNESIUM IODIDE IN THE PRESENCE OF Et2AlCl
Dzhemilev, U. M.,Ibragimov, A. G.,Morozov, A. B.,Muslukhov, R. R.,Tolstikov, G. A.
, p. 2350 - 2352 (2007/10/02)
A method has been developed for the methylenation of carbonyl compounds with methylenedimagnesium iodide in the presence of Et2AlCl in 35-70percent yield.In the presence of catalytic amounts of Ti and Pd complexes the yield of methylenation products is increased by 15-20percent.
Reaction Pathways of 3-(3'-Methylenecyclobutyl)propyl and 2-(3'-Methylenecyclobutyl)ethyl Radicals
Pigou, Paul E.
, p. 4943 - 4950 (2007/10/02)
Molecular mechanics (MM2) calculations were used to predict the efficacy and regiochemical outcome of radical cyclizations involving the title radicals and others with further substitution at C1 on the ring.The MM2 results were generally ratifi
