31039-88-0

Usage

InChI:InChI=1/C10H17NO/c1-10(2)6-8(11(3)4)5-9(12)7-10/h5H,6-7H2,1-4H3

Upstream product

• 126-81-8 dimedone 
• 124-40-3 dimethyl amine 
• 17530-69-7 3-chloro-5,5-dimethylcyclohex-2-en-1-one 
• 18922-00-4 5,5-dimethyl-3-oxocyclohex-1-en-1-yl methanesulfonate 
• 105244-30-2 2-(3,3-Bis-dimethylamino-allylidene)-5,5-dimethyl-cyclohexane-1,3-dione 
• 107-91-5 cyanoacetic acid amide 
• 90043-88-2 N-(5,5-dimethyl-3-oxocyclohex-1-enyl)-β-alanine ethyl ester 
• 74-88-4 methyl iodide 
• 873-95-0 1-amino-5,5-dimethylcyclohexen-3-one 
• 7357-70-2 Cyanothioacetamide 

Downstream Products

• 61049-65-8 2-(1-Benzoyl-3-oxo-3-phenyl-propyl)-5,5-dimethyl-cyclohexane-1,3-dione 
• 57966-11-7 3-N,N-dimethylamino-5,5-dimethyl-2-cyclohexene-1-thione 
• 82202-14-0 5,5-dimethyl-3-(phenyldimethylsilyl)-cyclohex-2-enone 

Relevant academic research and scientific papers

Formation of benzocyclobutenes from substituted oxocycloocta-2,8-diene-1,2-dicarboxylates Dedicated to the memory of Professor Alan Roy Katritzky

Substituted benzocyclobutenes were isolated from the reaction of substituted oxocycloocta-2,8-diene-1,2-dicarboxylates with DMAD which were themselves formed by the microwave assisted [2+2] cycloaddition of cyclic enaminones to dimethyl acetylenedicarboxylate. The high pressure hydrogenation of (1E,2Z)-dimethyl 3-(dimethylamino)-7-oxocycloocta-2,8-diene-1,2-dicarboxylate gave oxabicyclo[3.3.1]non-3-ene-2,3-dicarboxylates, while use of low pressure hydrogenation resulted in only the carbonyl group being reduced to give the corresponding hydroxyl derivative which was proposed as an intermediate of the oxabicyclo[3.3.1]nonanes formed using high pressure hydrogenation.

β-Acylvinyl-dicarbonyl-η5-cyclopentadienyl-iron Complexes

Reactions of β-chlorovinylcarbonyl compounds 10, 14, 16, 18, 20, 22, with sodium dicarbonyl-η5-cyclopentadienyl-ferrate (NaFp) furnish β-acylvinyl-dicarbonyl-η5-cyclopentadienyl-iron complexes 15, 17, 19, 21, 23 and binuclear iron co

Reactions Between Enaminones and Enones. Part 2. Alkylation of Enaminones with Acrylic Esters

The anion of 3-amino-5,5-dimethylcyclohex-2-enone (1) reacts with ethyl acrylate to give the product of C- or N-alkylation, depending on the conditions.With methyl methacrylate or methyl crotonate, the major product results from N-alkylation, but this rea

N-ALKYLATION OF ENAMINONES

The base catalyzed N-alkylation of a series of primary and secondary enaminones has been examined in detail.The enaminone anion was found to be a weak nucleophile.Best results were obtained in tetrahydrofuran or dioxane with sodium hydride and an alkyl io