31067-15-9

Basic information

• Product Name: 1,1,4-triphenyl-1-butanol
• Synonyms: 1,1,4-triphenyl-1-butanol
• CAS NO: 31067-15-9
• Molecular Weight: 302.416
• Mol File: 31067-15-9.mol

Chemical Properties

• CAS DataBase Reference: 1,1,4-triphenyl-1-butanol(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1,4-triphenyl-1-butanol(31067-15-9)
• EPA Substance Registry System: 1,1,4-triphenyl-1-butanol(31067-15-9)

Safety Data

• Hazardous Substances Data: 31067-15-9(Hazardous Substances Data)

Upstream product

• 119-61-9 benzophenone 
• 1462-75-5 3-phenylpropylmagnesium bromide 
• 5384-63-4 1,1-diphenylpentanol 
• 1726-12-1 1,1-diphenylpentane 
• 1530-11-6 1,1-diphenyl-pent-1-ene 
• 1454679-90-3 3-(adamantan-2-yl)-1,1-diphenylpropylhydroperoxide 
• 1454679-87-8 3-cyclohexyl-1,1-diphenylpropylhydroperoxide 
• 1454679-89-0 4-methyl-1,1-diphenylpentylhydroperoxide 
• 1454679-83-4 1,1-diphenylpentylhydroperoxide 
• 100-47-0 benzonitrile 
• 100-58-3 phenylmagnesium bromide 
• 1454679-74-3 3-(adamantan-2-yl)-1-phenylpropan-1-one 
• 1454679-75-4 3-(adamantan-2-yl)-1,1-diphenylpropan-1-ol 
• 55766-18-2 3-cyclohexyl-1,1-diphenylpropan-1-ol 

Downstream Products

• 38328-16-4 (1,4-diphenylbut-1-enyl)benzene 
• 33885-05-1 2,2,5-triphenylpentanoicacid 
• 111439-73-7 1,1-diphenyl-1,2,3,4-tetrahydronaphthalene 
• 91-01-0 1,1-Diphenylmethanol 
• 1454679-91-4 1,1,4-triphenylbutane-1,4-diol 
• 1454679-77-6 1,1,4-triphenylbutyl-1-hydroperoxide 

Relevant articles and documents

Iron-catalysed 1,2-aryl migration of tertiary azides

1,2-Aryl migration of α,α-diaryl tertiary azides was achieved by using the catalytic system of FeCl2/N-heterocyclic carbene (NHC) SIPr·HCl. The reaction generated aniline products in good yields after one-pot reduction of the migration-resultant imines.

Copper-catalyzed aerobic aliphatic C-H oxygenation with hydroperoxides

We report herein Cu-catalyzed aerobic oxygenation of aliphatic C-H bonds with hydroperoxides, which proceeds by 1,5-H radical shift of putative oxygen-centered radicals (O-radicals) derived from hydroperoxides followed by trapping of the resulting carboncentered radicals with molecular oxygen.

Behaviors of α-Fluorocarbenoids Derived from the Nucleophilic Desulfinylation of α-Chloro-α-fluoroalkyl Sulfoxides

2-Aryl-1-chloro-1-fluoroethyl sulfoxides underwent nucleophilic desulfinylation with PhMgBr to give (Z)-fluorostyrene derivatives in a very stereoselective manner (>33:1) via an α-fluorocarbene species.When treated with 3 equiv of PhLi in the presence of N,N,N',N'-tetramethylethylenediamine, they similarly formed fluorostyrenes as a stereoisomeric mixture (E:Z = 2:1), but with 1 equiv of PhLi 1-aryl-1-chloro-1-fluoroethanes were the major product.On the other hand, no formation of a fluoroalkene was observed in the desulfinylation of 1-chloro-1-fluoro-4-phenylbutyl sul foxide with the nucleophiles.In the latter reaction, oxidation and/or phenylation of the intermediate carbene were the main pathways.

One-pot synthesis of diarylalkylcarbinols and substituted derivatives through carbon monoxide insertion reactions into aryllithiums

The carbonylation of a THF solution of aryllithium (aryl = Ph, o-anisyl) in the presence of an alkyl bromide, RBr; at atmospheric pressure and -78 deg C, affords diarylalkylcarbinols in good yields.Alkyl chlorides do not react under similar experimental conditions.This feature makes the reaction particularly useful for the synthesisof alcohols functionalized in the alkyl chain through subsequent reactions of the diaryl(chloro)alkylcarbinols.The procedure can also be adapted to afford substituted cyclic ethers.If the reaction is carried out in the presence of dibromoalkanes, only one bromine atom reacts, affording diaryl(bromo)alkylcarbinols which are useful intermediates.With secondary and tertiary alkyl bromides diaryl alkyl ethers are obtained in variable yields.