31107-05-8

Basic information

• Product Name: N-(p-Chlorophenyl)hydrazone of Cyclohexanone
• Synonyms: N-(p-Chlorophenyl)hydrazone of Cyclohexanone
• CAS NO: 31107-05-8
• Molecular Weight: 222.718
• Mol File: 31107-05-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: N-(p-Chlorophenyl)hydrazone of Cyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: N-(p-Chlorophenyl)hydrazone of Cyclohexanone(31107-05-8)
• EPA Substance Registry System: N-(p-Chlorophenyl)hydrazone of Cyclohexanone(31107-05-8)

Safety Data

• Hazardous Substances Data: 31107-05-8(Hazardous Substances Data)

Upstream product

• 106-47-8 4-chloro-aniline 
• 108-94-1 cyclohexanone 
• 1073-69-4 N-4-chlorophenylhydrazine 

Downstream Products

• 36684-65-8 6-chloro-1,2,3,4-tetrahydrocarbazole 

Relevant articles and documents

MECHANISM OF THE FISCHER INDOLE SYNTHESIS. QUANTUM-CHEMICAL INTERPRETATION OF THE REARRANGEMENT OF SUBSTITUTED CYCLOHEXANONE ARYLHYDRAZONES TO TETRAHYDROCARBAZOLES

Calculations of a number of model structures within the scheme of Fischer indole synthesis were made on the basis of a bonding variant of perturbation theory in the self-consistent-field (SCF) MO LCAO method.A quantum-chemical interpretation of the effect of substituents on the course of the thermal process is given.The kinetics of the thermal and acid-catalyzed indolization of substituted cyclohexanone arylhydrazones to tetrahydrocarbazoles were studied by spectrophotometry.It was shown that the experimental data are in satisfactory agreement with the calculated values. It was concluded that a concerted mechanism ( a -sigma-tropic shift) for the step involving the formation of a carbon-carbon bond in the Fischer reaction is preferred.

Evaporator system comprising a stabilized pesticidal phosphoric acid ester and method for stabilizing such ester enclosed in an evaporator

An evaporator system adapted for emitting insect killing vapors of an insecticide therefrom and comprising a liquid or solid composition enclosed therein, said insecticide consisting in at least one volatile phosphoric acid ester which is stabilized by at least one diazene compound.