31179-52-9

Upstream product

• 104-92-7 1-bromo-4-methoxy-benzene 
• 7439-95-4 magnesium 

Downstream Products

• 94433-23-5 1-(3,4-Dimethoxy-phenyl)-1-dimethylamino-2-(4-methoxyphenyl)-ethan 
• 20498-67-3 1-phenyl-2-(4-methoxylphenyl)ethanol 
• 59363-12-1 1-chloro-4-(4-methoxyphenyl)-2-butanol 
• 77012-32-9 (E)-3-(6-(4-methoxyphenyl)-3-methylhex-3-enyl)-2,2-dimethyloxirane 
• 329978-33-8 (4R,5S)-3,4-dimethyl-1-[(S)-3-(3-fluorophenyl)-4-(4-methoxyphenyl)butanoyl]-5-phenylimidazolidin-2-one 
• 329978-41-8 (4R,5S)-3,4-dimethyl-1-[(S)-4-(4-methoxyphenyl)-3-(pyridin-3-yl)butanoyl]-5-phenylimidazolidin-2-one 
• 185416-72-2 [2-(4-Methoxyphenyl)methyl-6-methoxybenzothien-3-yl] [4-[2-(1-piperidinyl)ethoxy]phenyl]methanone 
• 613-37-6 4-methoxylbiphenyl 
• 53040-92-9 4-(4-tolyl)anisole 
• 58743-77-4 4'-methoxybiphenyl-4-carbonitrile 
• 834-14-0 p-benzylanizole 
• 1562625-73-3 1,3,4,5,6,7,8-heptafluoro-2-(4’-methoxyphenyl)naphthalene 
• 96066-61-4 1-(2-Propoxy-phenyl)-1-diethylamino-2-(4-methoxyphenyl)-ethan 

Relevant academic research and scientific papers

Fluoro-ene reaction versus [2+2] cycloaddition in the thermal C 2-C6 cyclization of enyne-allenes: An experimental and theoretical investigation

A series of fluoroalkyl-substituted enyne-allenes have been synthesized by a new route with the aim of elucidating the possibility of a fluoro-ene reaction via an intermediate fulvenyl diradical generated in the thermal C 2-C6 (Schmittel) cyclization reaction. As a result of the strong C-F bond, fluorine atom transfer was not observed. Instead, 1H-cyclobuta[a]indenes were formed in good yields despite the high strain energy. DFT calculations at the B3LYP level of theory indicated that although the fluoro-ene reaction is the most exothermic reaction available, cyclobutene formation is kinetically favored over the [1,5]-fluorine shift by 5-15 kcal mol-1 in various model compounds. Copyright