311805-52-4

Upstream product

• 311805-71-7 diethyl (6-benzyloxy-2-oxo-1-hexyl)phosphonate 
• 445380-24-5 (1'E,4R,5S)-4-(7'-benzyloxy-3'-oxohept-1'-en-1'-yl)-2,2,5-trimethyl-1,3-dioxolane 
• 54314-84-0 1-[(3-bromopropoxy)methyl]-benzene 
• 445380-25-6 (6E,8S,9S)-1-benzyloxy-8,9-dihydroxydec-6-en-5-one 

Downstream Products

• 71030-11-0 beta-zearalenol 
• 36455-72-8 α-zearalenol 
• 445380-32-5 4,6-bis[(2-methoxyethoxy)methyloxy]-2-[(1'E,6'S,10'S)-6',10'-dihydroxyundec-1'-en-1'-yl]benzoic acid 
• 445380-28-9 4,6-bis[(2-methoxyethoxy)methyloxy]-2-[(1'E,6'R,10'S)-6',10'-dihydroxyundec-1'-en-1'-yl]benzoic acid 
• 445380-31-4 methyl 4,6-bis[(2-methoxyethoxy)methyloxy]-2-[(1'E,6'S,10'S)-6',10'-dihydroxyundec-1'-en-1'-yl]benzoate 
• 445380-27-8 methyl 4,6-bis[(2-methoxyethoxy)methyloxy]-2-[(1'E,6'R,10'S)-6',10'-dihydroxyundec-1'-en-1'-yl]benzoate 
• 445380-26-7 methyl 4,6-bis[(2-methoxyethoxy)methyloxy]-2-[(1'E,6'R,10'S)-6',10'-bis(tert-butyldimethylsilyloxy)undec-1'-en-1'-yl]benzoate 
• 445380-30-3 methyl 4,6-bis[(2-methoxyethoxy)methyloxy]-2-[(1'E,6'S,10'S)-6',10'-bis(tert-butyldimethylsilyloxy)undec-1'-en-1'-yl]benzoate 
• 40790-12-3 (E)-(7R,11R)-2,4,11-Trihydroxy-7-methyl-7,8,9,10,11,12,13,14-octahydro-6-oxa-benzocyclotetradecen-5-one 

Relevant academic research and scientific papers

The use of π-allyltricarbonyliron lactone complexes in the synthesis of the resorcylic macrolides α- and β-zearalenol

A highly stereoselective synthesis of the natural products α- and β-zearalenol 1 and 2 has been achieved using π-allyltricarbonyliron lactone complexes to control the 1,5-stereochemical relationship of the oxygen functionalities found in these resorcylic macrolides.

The use of π-allyltricarbonyliron lactone complexes in the synthesis of the resorcylic macrolides α- and β-zearalenol

A highly stereoselective synthesis of α- and β-zearalenol 1 and 2 is accomplished utilising π-allyltricarbonyliron lactone complexes 5 and 6 to establish the 1,5-stereochemical relationship of oxygen functionalities present in the natural products. The Royal Society of Chemistry 2000.