311806-44-7Relevant articles and documents
Synthesis of 1,1,6,6-tetramethylphosphajulolidine
Edwards, Peter G.,Paisey, Stephen J.,Tooze, Robert P.
, p. 3122 - 3128 (2000)
The synthesis of fused tricyclic dialkyl(phenyl)phosphine was studied to verify the ligand influence upon the catalytic alkoxycarbonylation of propyne. The quantum mechanical calculations were performed to determine the ligand-derived influences upon catalytic activity. The results showed that the ellipticity of the bond was maximized by tethering the alkyl substituents to the ortho carbons of the aromatic ring.
