31202-09-2Relevant articles and documents
Metal triflate-catalyzed cyclization of arylvinylcarbinols: Formal synthesis of (±)-dichroanone and (±)-taiwaniaquinone H
Kakde, Badrinath N.,De, Subhadip,Dey, Dhananjay,Bisai, Alakesh
, p. 8176 - 8179 (2013/09/02)
A formal synthesis of diterpenoids viz. the taiwaniaquinoids (±)-dichroanone (1a) and (±)-taiwaniaquinone H (1b) possessing an all carbon quaternary stereocenter has been reported. The key step involves a metal triflate-catalyzed cyclization of arylvinylc