53621-45-7Relevant academic research and scientific papers
BISPHENOL COMPOSITION AND POLYCARBONATE RESIN
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, (2022/04/03)
A bisphenol composition includes 95% or more by mass of a bisphenol and 200 mass ppm or more of a compound represented by the following general formula (II): In formula (II), R21 and R22 denote a methyl group or a hydrogen atom; R22 is a methyl group when R21 is a hydrogen atom; R22 is a hydrogen atom when R21 is a methyl group; R23 to R25 independently denote a hydrogen atom or an alkyl group having 1 to 20 carbon atoms; and R23, R24, and R25 may be bonded or cross-linked between two of the groups. A method for producing a polycarbonate resin using the bisphenol composition is also described.
Iridium-Catalyzed C(sp3)?H Addition of Methyl Ethers across Intramolecular Carbon–Carbon Double Bonds Giving 2,3-Dihydrobenzofurans
Ohmura, Toshimichi,Kusaka, Satoshi,Torigoe, Takeru,Suginome, Michinori
supporting information, p. 4448 - 4453 (2019/09/16)
Intramolecular addition of an O-methyl C(sp3)?H bond across a carbon-carbon double bond occurs in the iridium-catalyzed reaction of methyl 2-(propen-2-yl)phenyl ethers. The Ir/(S)-DTBM-SEGPHOS catalyst promotes the reaction efficiently in toluene at 110–135 °C to afford 3,3-dimethyl-2,3-dihydrobenzofurans. Enantioselective C(sp3)?H addition is achieved in the reaction of methyl 2-(1-siloxyethenyl)phenyl ethers, affording enantioenriched 3-hydroxy-2,3-dihydrobenzofuran derivatives with up to 96% ee. (Figure presented.).
