3123-22-6Relevant academic research and scientific papers
Cycloadditions of cyclohexynes and cyclopentyne
Medina, Jose M.,McMahon, Travis C.,Jimnez-Oss, Gonzalo,Houk,Garg, Neil K.
, p. 14706 - 14709 (2014)
We report the strategic use of cyclohexyne and the more elusive intermediate, cyclopentyne, as a tool for the synthesis of new heterocyclic compounds. Experimental and computational studies of a 3-substituted cyclohexyne are also described. The observed regioselectivities are explained by the distortion/interaction model.
A photo-induced C-O bond formation methodology to construct tetrahydroxanthones
Xiao, Zheming,Cai, Shujun,Shi, Yingbo,Yang, Baochao,Gao, Shuanhu
, p. 5254 - 5257 (2014/05/06)
A metal-free, photo-induced C-O bond formation methodology was developed to construct tetrahydroxanthones. This mild and efficient methodology was based on intramolecular oxygen trapping of the reactive species produced by photolytic activation of a C-Cl
