312326-74-2

Upstream product

• 35875-02-6 2-methyl-2-phenylsulfanylbutan-3-one 
• 87727-28-4 (S)-2-tert-butyl-dimethyl-silanyloxy propanal 
• 87681-24-1 methyl (S)-2-(tert-butyldimethylsiloxy)propanoate 
• 63996-66-7 2-methyl-2-(phenylthio)propanal 
• 58468-92-1 (2RS)-3-methyl-3-phenylsulfanylbutan-2-ol 

Downstream Products

• 531557-80-9 (3S,5S,6S)-2-methyl-2-phenylsulfanyl-6-(tert-butyldimethylsiloxy)heptane-3,5-diol 
• 312326-84-4 (2S,3S,5R)-6-Methyl-6-phenylsulfanyl-heptane-2,3,5-triol 

Relevant academic research and scientific papers

Scope and limitation of the [1,2]-phenylsulfanyl (PhS) migration in the synthesis of tetrahydrofurans and tetrahydropyrans from common triol precursors

Scope and limitation of the [1,2]-phenylsulfanyl (PhS) migration in the synthesis of tetrahydrofurans and tetrahydropyrans from common triol precursors were discussed. Triols containing three secondary hydroxy groups were rearranged using either toluene-p

Scope and limitation of the [1,2]-phenylsulfanyl (PhS) migration in the asymmetric synthesis of tetrahydrofurans and tetrahydropyrans from common triol precursors

Triols containing three secondary hydroxy groups were reacted with either (i) toluene p-sulfonic acid or (ii) trimethylorthoacetate-pyridinium toluene p-sulfonate followed by toluene p-sulfonic acid.