35875-02-6Relevant academic research and scientific papers
Diphenyl diselenide-assisted α-phenylthiolation of carbonyl compounds with diphenyl disulfide
Anbou, Hiroaki,Umeda, Rui,Nishiyama, Yutaka
experimental part, p. 1248 - 1250 (2012/01/31)
For the cesium carbonate-catalyzed α-phenylthiolation of carbonyl compounds with diphenyl disulfide, the yields of the α-phenylthio carbonyl compounds were dramatically improved by the addition of a catalytic amount of diphenyl diselenide.
Scope and limitation of the [1,2]-phenylsulfanyl (PhS) migration in the synthesis of tetrahydrofurans and tetrahydropyrans from common triol precursors
House, David,Kerr, Fraser,Warren, Stuart
, p. 2652 - 2662 (2007/10/03)
Scope and limitation of the [1,2]-phenylsulfanyl (PhS) migration in the synthesis of tetrahydrofurans and tetrahydropyrans from common triol precursors were discussed. Triols containing three secondary hydroxy groups were rearranged using either toluene-p
A Novel Rearrangement of Vinyl Sulphoxides
Lucchi, Ottorino De,Marchioro, Gaetano,Modena, Giorgio
, p. 513 - 514 (2007/10/02)
Acid catalysed isopropenyl acetate treatment of vinyl sulphoxides results in a formal oxygen transposition from sulphur to the β-olefinic carbon via a presumed -sigmatropic rearrangement of an acetoxysulphonium salt.
