312539-66-5Relevant academic research and scientific papers
Reactions of acylzirconocene chloride with nucleophiles: Bimodal reactivity at β- and acyl carbons of α,β-unsaturated acylzirconocene chloride
Hanzawa,Narita,Kaku-uchi,Taguchi
, p. 7525 - 7528 (2000)
Reactions of α,β-unsaturated acylzirconocene chloride with nucleophiles showed novel bimodal reactivity at the β- and acyl carbons depending upon the nucleophile employed, and the formation of ketone α,β-dianionic species was also observed. (C) 2000 Elsev
Primary-amine-catalyzed enantioselective intramolecular aldolizations
Zhou, Jian,Wakchaure, Vijay,Kraft, Philip,List, Benjamin
supporting information; experimental part, p. 7656 - 7658 (2009/04/10)
Aldol cyclodehydration of 4-substituted-2,6-heptanediones leads to enantiomerically enriched 5-substituted-3-methyl-2-cyclohexene-1-ones, which serve as perfume ingredients and valuable synthetic building blocks.Primary amines derived from cinchona alkalo
