31294-92-5Relevant academic research and scientific papers
Direct bromination and iodination of non-activated alkanes by hypohalite reagents
Montoro, Raul,Wirth, Thomas
, p. 1473 - 1478 (2007/10/03)
The direct functionalisation of alkanes through bromination and iodination has been successfully achieved. The combination of stoichiometric mixtures of elemental halogen and sodium alkoxides leads to the formation of alkyl hypobromites and hypoiodites as reagents. The halogenation occurs without external photostimulation under thermal reaction conditions. Georg Thieme Verlag Stuttgart.
Direct Iodination of Alkanes
Montoro, Raul,Wirth, Thomas
, p. 4729 - 4731 (2007/10/03)
(Matrix presented) A cheap and efficient iodination of hydrocarbons can be achieved by generating tert-butyl hypoiodite from iodine and sodium tert-butoxide. The alkane is reactant and solvent, and this metal-free process provides a clean solution for their direct iodination.
A new direct homolytic iodination reaction of alkanes by perfluoroalkyl iodides
Liguori, Lucia,Bjorsvik, Hans-Rene,Bravo, Anna,Fontana, Francesca,Minisci, Francesco
, p. 1501 - 1502 (2007/10/03)
A new method for the direct free-radical chain iodination of alkanes by perfluoroalkyl iodides is described.
