313220-25-6

Upstream product

• 201534-23-8 allyl 2,3-di-O-benzoyl-4,6-benzylidene-α-D-glucopyranoside 
• 98-88-4 benzoyl chloride 
• 65987-12-4 1-O-allyl-4,6-O-benzylidene-α-D-glucopyranoside 
• 155786-53-1 allyl 2,3-di-O-benzoyl-α-D-glucopyranoside 

Relevant academic research and scientific papers

A facile synthesis of the tetrasaccharide repeating unit of mannoglucan from Microellobosporia grisea

A facile synthesis of the tetrasaccharide repeating unit of mannoglucan from Microellobosporia grisea was achieved through coupling of 4,6-O-benzylidene-1,2-O-ethylidene-α-D-glucopyranose with per-O-benzoylated mannopyranosyl trichloroacetimidate, followed by debenzylidenation, selective 6-O-mannopyranosylation, then hydrolysis of the 1,2-O-ethylidene group, 1,2-O-acetylation and conversion to the 1-trichloroacetimidate, and subsequent condensation of the activated trisaccharide with allyl 2,3,6-tri-O-benzoyl-α-D-glucopyranoside. (C) 2000 Elsevier Science Ltd.