31349-66-3

Basic information

• Product Name: methyl 2-((phenethylcarbamoyl)oxy)benzoate
• Synonyms: methyl 2-((phenethylcarbamoyl)oxy)benzoate
• CAS NO: 31349-66-3
• Molecular Weight: 299.326
• Mol File: 31349-66-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl 2-((phenethylcarbamoyl)oxy)benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-((phenethylcarbamoyl)oxy)benzoate(31349-66-3)
• EPA Substance Registry System: methyl 2-((phenethylcarbamoyl)oxy)benzoate(31349-66-3)

Safety Data

• Hazardous Substances Data: 31349-66-3(Hazardous Substances Data)

Upstream product

• 1943-82-4 phenethyl isocyanate 
• 119-36-8 methyl salicylate 
• 82091-12-1 dimethyl 2,2’-(carbonylbis(oxy))dibenzoate 
• 64-04-0 phenethylamine 
• 33564-94-2 2-chlorocarbonyloxy-benzoic acid methyl ester 

Downstream Products

• 82091-12-1 dimethyl 2,2’-(carbonylbis(oxy))dibenzoate 
• 1196-38-9 3,4-dihydroisoquinolin-1(2H)-one 
• 119-36-8 methyl salicylate 
• 64-04-0 phenethylamine 
• 22245-96-1 7-nitro-3,4-dihydro-2H-isoquinolin-1-one 
• 52007-97-3 N-isopropyl-N-(2-phenylethyl)amine 

Relevant articles and documents

Facile synthesis of 5-To 7-membered benzolactam compounds via strongly facilitated electrophilic aromtic substitution reaction

We employed our system to activate aromatic ring-Tethered carbamate compounds with trifluoromethanesulfonic acid to obtain benzolactams with 5-To 7-membered rings, and examined the substrate scope and limitations of this activation method. In 5-membered ring formation, a halogen group on the aromatic ring did not greatly affect the reaction yield, but other electron-donating groups inhibited the cyclization reaction, and various side-reactions occurred. In 7-membered ring formation, eletron-donating groups on aromatic ring promoted the cyclization reaction, but cyclization of electron-deficient aromatic rings did not proceed well. The 6-membered ring formation reaction showed the greatest substrate generality.