3137-11-9

Usage

Explanation

The molecular formula represents the number of atoms of each element present in a molecule of 1-(4-nitro-benzyl)-naphthalene.

Explanation

The core structure of 1-(4-nitro-benzyl)-naphthalene is a naphthalene molecule, which is a fused pair of benzene rings. A benzyl group (C6H5-CH2-) and a nitro group (-NO2) are attached to the naphthalene core.

Explanation

1-(4-nitro-benzyl)-naphthalene has distinct chemical and structural properties that make it useful in various applications, such as organic synthesis and chemical research.

Explanation

Due to its unique properties, 1-(4-nitro-benzyl)-naphthalene is used in the synthesis of various organic compounds, as well as in the production of industrial products and pharmaceuticals.

Explanation

1-(4-nitro-benzyl)-naphthalene is significant in various scientific and industrial applications due to its versatility and the diverse range of products and materials that can be derived from it.

Structure

Naphthalene core with a benzyl group and a nitro group attached

Chemical properties

Unique chemical and structural properties

Applications

Organic synthesis, chemical research, industrial products, and pharmaceuticals

Potential applications

Materials science and as a precursor for the synthesis of other organic compounds

Importance

Wide range of uses in scientific and industrial fields

Upstream product

• 91-20-3 naphthalene 
• 4450-68-4 4-nitrobenzyl tosylate 
• 90-11-9 1-Bromonaphthalene 
• 99-99-0 1-methyl-4-nitrobenzene 
• 55831-10-2 1-(Fluoromethyl)naphthalene 
• 24067-17-2 4-nitrophenylboronic acid 
• 13922-41-3 1-Naphthylboronic acid 
• 100-11-8 1-bromomethyl-4-nitro-benzene 

Downstream Products

• 611-45-0 1-Benzyl-naphthalene 

Relevant academic research and scientific papers

Palladium and Nickel Catalyzed Suzuki Cross-Coupling with Alkyl Fluorides

Suzuki cross-coupling of benzylic and unactivated aliphatic fluorides with aryl- and alkenylboronic acids has been achieved via mechanistically distinct Pd and Ni catalyzed pathways that outperform competing protodeboronation, β-hydride elimination, and h

Insights into the role of new palladium pincer complexes as robust and recyclable precatalysts for suzuki-miyaura couplings in neat water

Suzuki-Miyaura biaryl and diarylmethane syntheses via the coupling of arylboronic acids with aryl and arylmethyl bromides are performed in water by means of two new CNC-type palladium pincer complexes. Good to excellent results (including high TON values and extended recycling procedures) are obtained in most cases for a range of electronically dissimilar halides and boronic acids. On the basis of a series of kinetics studies, transmission electron microscopy (TEM), mercury drop tests, and quantitative poisoning experiments, the real role of the latter palladacycles, closely linked to the formation and active participation of palladium nanoparticles, is discussed.

A nonsymmetric pincer-catalyzed Suzuki-Miyaura arylation of benzyl halides and other nonactivated unusual coupling partners

(Chemical Equation Presented) The catalytic activity of a PCN-type palladium pincer complex is evaluated in the construction of C(sp 2)-C(sp2) and C(sp2)-C(sp3) bonds by Suzuki-Miyaura cross-couplings employing nontypical substrates such as benzyl halides, α-haloenones, or alkylboronic acids as coupling partners. Most of the reported reactions are achieved in aqueous media, with all of the advantages implied.

Palladium-catalyzed coupling reaction of 4-alkylnitrobenzenes with aryl bromides at their benzylic position

4-Alkylnitrobenzenes effectively undergo coupling with aryl bromides at their benzylic position in the presence of a palladium catalyst and a base to give the corresponding mono- and/or di-arylated products in good yields.