31396-84-6

Basic information

• Product Name: ZINC 1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-HEXADECAFLUORO-29H,31H-PHTHALOCYANINE
• Synonyms: ZINC 1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-HEXADECAFLUORO-29H,31H-PHTHALOCYANINE;zinc 1,2,3,4,8,9,10,11,15,16,17,18,22,23;ZINC 1,2,3,4,8,9,10,11,15,16,17,18,22,23 , 24,25-HEXADECAFLUORO-PHTHALOCYANINE;Zinc 1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-hexadecafluoro-29H,31H-phthalocyanine Dye content 90 %
• CAS NO: 31396-84-6
• Molecular Formula: C₃₂F₁₆N₈Zn
• Molecular Weight: 865.76
• Product Categories: Infrared (IR) DyesPhotonic and Optical Materials;Organic Electronics and Photonics;Photonic and Optical Materials;Phthalocyanine and Porphyrin Dyes;Phthalocyanines
• Mol File: 31396-84-6.mol

Chemical Properties

• Melting Point: >300 °C(lit.)
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Appearance: /
• Density: g/cm³
• CAS DataBase Reference: ZINC 1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-HEXADECAFLUORO-29H,31H-PHTHALOCYANINE(CAS DataBase Reference)
• NIST Chemistry Reference: ZINC 1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-HEXADECAFLUORO-29H,31H-PHTHALOCYANINE(31396-84-6)
• EPA Substance Registry System: ZINC 1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-HEXADECAFLUORO-29H,31H-PHTHALOCYANINE(31396-84-6)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26
• WGK Germany: 3
• Hazardous Substances Data: 31396-84-6(Hazardous Substances Data)

Usage

Uses

Used in a study of photodynamic tumor therapy.

InChI:InChI=1/C32F16N8.Zn/c33-9-1-2(10(34)18(42)17(9)41)26-49-25(1)53-27-3-4(12(36)20(44)19(43)11(3)35)29(50-27)55-31-7-8(16(40)24(48)23(47)15(7)39)32(52-31)56-30-6-5(28(51-30)54-26)13(37)21(45)22(46)14(6)38;/q-2;+2

Upstream product

• 1835-65-0 Tetrafluorophthalonitrile 
• 7440-66-6 zinc 
• 7699-45-8 zinc dibromide 
• 10139-47-6 zinc(II) iodide 
• 557-34-6 zinc diacetate 
• 5970-45-6 zinc(II) acetate dihydrate 
• 827-08-7 1,2-dibromo-3,4,5,6-tetrafluorobenzene 
• 1953-99-7 tetrachlorophthalonitrile 
• 7646-85-7 zinc(II) chloride 

Downstream Products

• 681146-92-9 hexadecacyanophthalocyaninato zinc(II) 
• 1215178-94-1 C₂₂₄H₄₀₀N₈S₁₆Zn 

Relevant articles and documents

High-potential perfluorinated phthalocyanine-fullerene dyads for generation of high-energy charge-separated states: Formation and photoinduced electron-transfer studies

High oxidation potential perfluorinated zinc phthalocyanines (ZnF nPcs) are synthesised and their spectroscopic, redox, and light-induced electron-transfer properties investigated systematically by forming donor-acceptor dyads through metal-lig

Dye compounds and resin composition for color filter comprising the same

The present invention relates to a phthalocyanine compound which is represented by chemical formula 1 and is used in a color filter. According to the present invention, a resin composition containing the phthalocyanine compound exhibits excellent solubility in an organic solvent such as propylene glycol methyl ether acetate (PGMEA). In addition, the resin composition also shows high permeability as well. Thus, production of the excellent color filter is possible by using the resin composition.COPYRIGHT KIPO 2016

MICROWAVE-ASSISTED SYNTHESIS OF PERFLUOROPHTHALOCYANINE MOLECULES

Advantageous microwave-assisted methods for synthesis of fluorinated phthalocyanines are provided. The microwave-assisted methods offer enhanced yields, substantially eliminate reaction solvents, and facilitate purification relative to conventional synthesis techniques. Typical implementation involve a reaction mixture that includes perfluoro-phthalonitrile that is reacted in a vessel with application of microwave energy for a reaction period sufficient to yield a fluorinated phthalocyanine. The fluorinated phthalocyanines synthesized according to the disclosed microwave-assisted methods have wide ranging applications, e.g., corrosion-related applications, coating-related applications, catalysis, and the production of optical and electronic materials.

Rational design of a reactive yet stable organic-based photocatalyst

Zinc perfluoro-fluoroalkyl-phthalocyanine, synthesized in high yield, does not exhibit electron loss, does not aggregate in solution, is photostable and produces 1O2 in very high quantum yields. Aerobic photo-oxygenation of an external substrate occurs without catalyst self-oxidation. The encapsulation of a metal center in a refractory organic environment could guide the design of other viable catalysts for oxygenation of substrates either for synthesis or for oxidative destruction of organic or biological molecules, under reaction conditions that include the use of only air and light. The Royal Society of Chemistry 2009.

Fluorinated phthalocyanines as molecular semiconductor thin films

Thin films of pefluorinated phthalocyanines F16Pc show promise as molecular semiconductors in organic field effect transistors. A review is provided of growth studies and electrical characterization of presently discussed materials. Using this state-of-the-art as a starting point the synthesis and position of energy levels of partly fluorinated Zn(II) phthalocyanines is described. Growth characteristics of vapour-deposited thin films on inorganic and organic dielectrics are studied. Possibilities to use fluorinated phthalocyanines in technical applications of OFET are discussed.

Electronic energy levels of organic dyes on silicon: A photoelectron spectroscopy study of ZnPc, F16ZnPc, and ZnTPP on p-Si(111):H

Alignment of energy levels and chemical interaction of the organic pigments ZnPc, substituted F16ZnPc, and ZnTPP on H-terminated Si(111) have been deduced from valence band and core level photoelectron spectroscopy with high surface sensitivity for coverage below and in the monolayer region. Hydrogen-terminated Si(111) was prepared in UHV. The dyes have been purified by zone sublimation and were deposited at room temperature by PVD. SXPS taken at the synchrotron BESSY shows physisorption of the dye molecules; chemical shifts indicating strong interactions with the substrate have not been observed. The maxima of the HOMO photoemission of ZnPc, F16ZnPc, and ZnTPP are measured at 0.45, 1.55, and 1.0 eV below the Si valence band maximum. These experimental values are compared to theoretical values and are related to the position of the optical gap, the transport gap, and the redox potentials of the ground and excited state.