314022-46-3Relevant academic research and scientific papers
Chiral sulfoxide ligands bearing nitrogen atoms as stereocontrollable coordinating elements in palladium-catalyzed asymmetric allylic alkylations
Hiroi, Kunio,Suzuki, Yoshio,Abe, Ikuko,Hasegawa, Yutaka,Suzuki, Kenji
, p. 3797 - 3817 (1998)
Palladium-catalyzed asymmetric allylic alkylations were studied by using chiral sulfoxide ligands bearing nitrogen atoms as coordinating elements, such as chiral α-sulfinylacetamides, β or γ-amino sulfoxides, and β- sulfinyl sulfonamides. The effects of t
Nickel or phenanthroline mediated intramolecular arylation of sp 3 C-H bonds using aryl halides
Wertjes, William C.,Wolfe, Lydia C.,Waller, Peter J.,Kalyani, Dipannita
supporting information, p. 5986 - 5989 (2014/01/06)
The development of the intramolecular arylation of sp3 C-H bonds adjacent to nitrogen using aryl halides is described. Arylation was accomplished using either Ni(COD)2 or 1,10-phenanthroline in substoichiometric amounts, and the reaction conditions were applied to a variety of electronically differentiated benzamide substrates. Preliminary studies suggest a mechanism involving aryl and alkyl radical intermediates.
