314263-97-3

Upstream product

• 123-08-0 4-hydroxy-benzaldehyde 
• 108740-74-5 phenyl 2,3,4-tri-O-acetyl-1-thio-α-L-rhamnopyranoside 
• 75-52-5 nitromethane 
• 88086-87-7 4-(2',3',4'-tri-O-acetyl-α-L-rhamnopyranosyloxy)benzaldehyde 

Relevant academic research and scientific papers

First synthesis of an O-glycosylated glucosinolate isolated from Moringa oleifera

Starting from L-rhamnose, the first synthesis of the major glucosinolate (1) isolated from Moringa oleifera seeds was effected in seven steps. (C) 2000 Elsevier Science Ltd.

Glucosinolate chemistry: Synthesis of O-glycosylated derivatives of glucosinalbin

The synthesis of the major glucosinolate of Moringa oleifera and of other non-natural O-glycosylated derivatives of glucosinalbin is reported. The synthetic sequence applied, which involves the conversion of carbohydrate-based nitrostyrenes into the key thiohydroximates, appears to be sufficiently versatile to synthesize a range of glucosinolates bearing a glycosylated phenolic function. We synthesized analogues of the naturally occurring L-rhamnoside 1 with a view to estimating the importance of this phenol-protecting sugar moiety in modulating the biological activity of the parent glucosinolate and related breakdown products.