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[Ru(H2)(Cl)2(P(C6H11)3)2] is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

314281-12-4

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314281-12-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 314281-12-4 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 3,1,4,2,8 and 1 respectively; the second part has 2 digits, 1 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 314281-12:
(8*3)+(7*1)+(6*4)+(5*2)+(4*8)+(3*1)+(2*1)+(1*2)=104
104 % 10 = 4
So 314281-12-4 is a valid CAS Registry Number.

314281-12-4Upstream product

314281-12-4Downstream Products

314281-12-4Relevant academic research and scientific papers

Hydrogenolysis of a ruthenium carbene complex to yield dihydride-dihydrogen tautomers: Mechanistic implications for tandem ROMP-hydrogenation catalysis

Drouin,Yap,Fogg

, p. 5412 - 5414 (2000)

Conversion of Grubbs's catalyst 1 into a hydrogenation catalyst is described. Hydrogenolysis of the Rucarbene bond in CH2Cl2 yields Ru(IV) species 2; in other solvents, a mixture of 2 and its dihydrogen tautomer 4 is formed, even in the presence of base. Further reaction gives hydridochloro complex RuHCl(H2)(PCy3)2 3, which reverts to 2 in CH2Cl2.

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