31465-44-8Relevant academic research and scientific papers
Unexpected oxadi-π-methane rearrangement of β,γ-unsaturated aldehydes
Armesto, Diego,Ortiz, Maria J.,Romano, Santiago,Agarrabeitia, Antonia R.,Gallego, Mar G.,Ramos, Ana
, p. 1459 - 1466 (2007/10/03)
The oxadi-π-methane rearrangement (ODPM) is considered to represent the normal photochemical behavior of β,γ-unsaturated ketones in the triplet excited π,π* state. However, the usual photoreactivity reported for the majority of β,γ-unsaturated aldehydes i
The oxa-di-π-methane rearrangement of β,γ-unsaturated aldehydes
Armesto, Diego,Ortiz, Maria J.,Ramano, Santiago
, p. 965 - 968 (2007/10/02)
As far as we are aware, there are only two examples of oxa-di-π-methane (ODPM) rearrangement with β,γ-unsaturated aldehydes. However, we have discovered four other cases of this reaction, taking place with 1-methyl-3-phenyl-2-cyclohexene-1-carbaldehyde, 1
