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31469-16-6

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  • Silane,[(1-ethoxy-2-methyl-1-propen-1-yl)oxy]trimethyl-

    Cas No: 31469-16-6

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31469-16-6 Usage

General Description

1-Ethoxy-2-methyl-1-(trimethylsiloxy)-1-propene is a chemical compound of the organic compound class. It is a derivative of propene, a basic alcohol, which has been modified by the addition of a trimethylsiloxy group, an ethoxy group, and an additional methyl group giving it a more complex structure. This chemical is used in the field of synthetic organic chemistry. Due to its reactivity, it is often employed as a reagent or as a precursor to other, more elaborate, compounds. Its exact properties will depend on various external conditions such as temperature and pressure, and the presence of other chemicals. As with many organic compounds, it should be handled with caution due to its potentially hazardous nature.

Check Digit Verification of cas no

The CAS Registry Mumber 31469-16-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,1,4,6 and 9 respectively; the second part has 2 digits, 1 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 31469-16:
(7*3)+(6*1)+(5*4)+(4*6)+(3*9)+(2*1)+(1*6)=106
106 % 10 = 6
So 31469-16-6 is a valid CAS Registry Number.

31469-16-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name (1-ethoxy-2-methylprop-1-enoxy)-trimethylsilane

1.2 Other means of identification

Product number -
Other names 1-ethoxy-2-methyl-1-trimethylsiloxyprop-1-ene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:31469-16-6 SDS

31469-16-6Relevant articles and documents

Total synthesis of (-)-rhizopodin

Dalby, Stephen M.,Goodwin-Tindall, Jake,Paterson, Ian

, p. 6517 - 6521 (2013)

Core assembly: The total synthesis of the myxobacterial metabolite rhizopodin, a potent actin-binding anticancer agent, has been achieved. The modular synthesis utilizes a common C1-C22 monomeric unit to assemble the dimeric 38-membered macrodiolide core, which was elaborated by a bidirectional boron-mediated aldol reaction to install the characteristic side-chains. The final global deprotection was critically dependent on the correct choice of silyl protecting groups at C16/C16′. Copyright

C?Boron Enolates Enable Palladium Catalyzed Carboboration of Internal 1,3-Enynes

Wang, Ziyong,Wu, Jason,Lamine, Walid,Li, Bo,Sotiropoulos, Jean-Marc,Chrostowska, Anna,Miqueu, Karinne,Liu, Shih-Yuan

supporting information, p. 21231 - 21236 (2021/09/02)

A new family of carbon-bound boron enolates, generated by a kinetically controlled halogen exchange between chlorocatecholborane and silylketene acetals, is described. These C?boron enolates are demonstrated to activate 1,3-enyne substrates in the presence of a Pd0/Senphos ligand complex, resulting in the first examples of a carboboration reaction of an alkyne with enolate-equivalent nucleophiles. Highly substituted dienyl boron building blocks are produced in excellent site-, regio-, and diastereoselectivity by the described catalytic cis-carboboration reaction.

Gallium trihalide catalyzed sequential addition of two different carbon nucleophiles to esters by using silyl cyanide and ketene silyl acetals

Inamoto, Yoshihiro,Kaga, Yuta,Nishimoto, Yoshihiro,Yasuda, Makoto,Baba, Akio

supporting information, p. 11664 - 11668 (2014/10/15)

A sequential addition of silyl cyanide and ketene silyl acetals to esters was achieved by a gallium trihalide catalyst to produce β-cyano-β- siloxy esters. This is the first example of the sequential addition of two different carbon nucleophiles to esters. The employment of lactones provided α,α-disubstituted cyclic ethers with a cyano group and an ester moiety. A variety of esters and lactones are applicable to this reaction system.

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