3149-60-8

Upstream product

• 77-78-1 dimethyl sulfate 
• 1464-44-4 phenyl-β-D-glucopyranoside 

Downstream Products

• 132840-93-8 (R)-1-[2-((2S,3R,4S,5R,6R)-3,4,5-Trimethoxy-6-methoxymethyl-tetrahydro-pyran-2-yloxy)-cyclohexa-2,5-dienyl]-propan-2-ol 
• 132840-93-8 (S)-1-[2-((2S,3R,4S,5R,6R)-3,4,5-Trimethoxy-6-methoxymethyl-tetrahydro-pyran-2-yloxy)-cyclohexa-2,5-dienyl]-propan-2-ol 
• 132840-95-0 tert-Butyl-dimethyl-{3-[2-((2S,3R,4S,5R,6R)-3,4,5-trimethoxy-6-methoxymethyl-tetrahydro-pyran-2-yloxy)-cyclohexa-2,5-dienyl]-propoxy}-silane 
• 132841-00-0 (2R,3R,4S,5R,6S)-3,4,5-Trimethoxy-2-methoxymethyl-6-[(S)-6-(3-nitro-propyl)-cyclohexa-1,4-dienyloxy]-tetrahydro-pyran 
• 132841-01-1 (4aS,7aS,7bS)-5-((2S,3R,4S,5R,6R)-3,4,5-Trimethoxy-6-methoxymethyl-tetrahydro-pyran-2-yloxy)-3,4,4a,7,7a,7b-hexahydro-indeno[1,7-cd]isoxazole 
• 132840-97-2 3-[(S)-2-((2S,3R,4S,5R,6R)-3,4,5-Trimethoxy-6-methoxymethyl-tetrahydro-pyran-2-yloxy)-cyclohexa-2,5-dienyl]-propionaldehyde 
• 132840-92-7 2-[2-((2S,3R,4S,5R,6R)-3,4,5-Trimethoxy-6-methoxymethyl-tetrahydro-pyran-2-yloxy)-cyclohexa-2,5-dienyl]-ethanol 
• 115432-10-5 (2S,3R,4S,5R,6R)-2-(6-Isopropyl-2-methyl-cyclohexa-1,4-dienyloxy)-3,4,5-trimethoxy-6-methoxymethyl-tetrahydro-pyran 
• 115432-08-1 (2S,3R,4S,5R,6R)-2-(6-Isopropyl-cyclohexa-1,4-dienyloxy)-3,4,5-trimethoxy-6-methoxymethyl-tetrahydro-pyran 
• 115432-07-0 (2S,3R,4S,5R,6R)-2-(6-Benzyl-cyclohexa-1,3-dienyloxy)-3,4,5-trimethoxy-6-methoxymethyl-tetrahydro-pyran 
• 115432-06-9 (2S,3R,4S,5R,6R)-2-(6-Benzyl-cyclohexa-1,4-dienyloxy)-3,4,5-trimethoxy-6-methoxymethyl-tetrahydro-pyran 
• 115432-09-2 (2S,3R,4S,5R,6R)-2-(6-Isopropyl-cyclohexa-1,3-dienyloxy)-3,4,5-trimethoxy-6-methoxymethyl-tetrahydro-pyran 
• 115431-90-8 1-(per-O-methyl-β-D-glucopyranosyloxy)-1,4-cyclohexadiene 

Relevant academic research and scientific papers

REGIO- AND STEREOSELECTIVE CONTROL IN THE ALKYLATION OF 1-ALKOXY-1,4-CYCLOHEXADIENES BY THE CHIRAL AUXILIARY APPROACH. ENANTIOSELECTIVE SYNTHESIS OF PRECURSORS FOR CIS-HYDRINDANES.

A method is described for the regio- and diastereoselective alkylation of optically active 1-alkoxy-1,4-cyclohexadienes.Reaction conditions were optimised for substrates 4a with the per-O-methyl-β-D-glucopyranosyl group as chiral auxiliary.In the methylat

CHELATION CONTROLLED REGIOSELECTIVE ALKYLATION AND 1,4 CHIRALITY TRANSFER IN OPTICALLY ACTIVE 1-ALKOXY-1,4-CYCLOHEXADIENES

Chelation controlled alkylation of optically active 1-alkoxy-1,4-cyclohexadienes leads to a mixture of 1,4-cyclohexadienes 4a-c and 1,3-cyclohexadienes 5a-c.The regio- and diastereoselectivities depend upon the nature of the chiral auxiliary and the react