31508-07-3Relevant academic research and scientific papers
Catalytic Regio- and Enantioselective Proton Migration from Skipped Enynes to Allenes
Wei, Xiao-Feng,Wakaki, Takayuki,Itoh, Taisuke,Li, Hong-Liang,Yoshimura, Takayoshi,Miyazaki, Aya,Oisaki, Kounosuke,Hatanaka, Miho,Shimizu, Yohei,Kanai, Motomu
supporting information, p. 585 - 599 (2019/03/11)
Chiral allenes are highly valuable as versatile synthetic intermediates and core skeletons of various functional organic molecules. Despite marked recent advances, the straightforward catalytic enantioselective synthesis of hydrocarbon allenes from readil
One-Pot Synthesis of Decahydropyrene via Tandem C-H Activation/Intramolecular Diels-Alder/1,3-Dipolar Cycloaddition
Lin, Hui,Dong, Lin
supporting information, p. 5524 - 5527 (2016/11/17)
A novel decahydropyrene synthesis has been successfully developed involving a tandem rhodium-catalyzed C-H activation/intramolecular Diels-Alder reaction/1,3-dipolar cycloaddition cascade process by using diazole as a traceless directing group. The advantage of this one-pot strategy is a quite simple, efficient, highly stereoselective, and unique product structure.
Rhodium-catalysed arylative annulation of 1,4-enynes with arylboronic acids
Matsuda, Takanori,Watanuki, Shoichi
supporting information, p. 702 - 705 (2015/02/19)
The rhodium(I)-catalysed arylative annulation of 1,4-enynes with arylboronic acids was investigated. The reaction was found to proceed via an addition-1,4-rhodium migration-addition sequence, affording the corresponding 1,1-disubstituted 3-(arylmethylene)indanes.
Synthesis of polycyclic compounds utilizing the nickel-catalysed alkynylstannylation of 1,2-dienes
Shirakawa, Eiji,Nakao, Yoshiaki,Tsuchimoto, Teruhisa,Hiyama, Tamejiro
, p. 1962 - 1963 (2007/10/03)
Polycyclic compounds having linearly-fused six-membered rings can be readily prepared by various modes of cyclization from dienediynes, which were synthesized through the nickel-catalysed alkynylstannylation of 1,2-dienes followed by the palladium-catalysed oxidative homocoupling of the resulting alkenylstannanes.
