3360-54-1

Basic information

• Product Name: (1-BROMOMETHYL-VINYL)-BENZENE
• Synonyms: (1-BROMOMETHYL-VINYL)-BENZENE;(3-BroMoprop-1-en-2-yl)benzene
• CAS NO: 3360-54-1
• Molecular Formula: C₉H₉Br
• Molecular Weight: 197.07176
• Mol File: 3360-54-1.mol
• Article Data: 118

Chemical Properties

• Melting Point: 29 °C(Solv: ethanol (64-17-5))
• Boiling Point: 230.9°C at 760 mmHg
• Flash Point: 99.7°C
• Appearance: /
• Density: 1.327g/cm³
• Vapor Pressure: 0.0973mmHg at 25°C
• Refractive Index: 1.562
• CAS DataBase Reference: (1-BROMOMETHYL-VINYL)-BENZENE(CAS DataBase Reference)
• NIST Chemistry Reference: (1-BROMOMETHYL-VINYL)-BENZENE(3360-54-1)
• EPA Substance Registry System: (1-BROMOMETHYL-VINYL)-BENZENE(3360-54-1)

Safety Data

• Hazardous Substances Data: 3360-54-1(Hazardous Substances Data)

Usage

General Description

(1-Bromomethyl-vinyl)-benzene, also known as styrene bromomethyl vinylbenzene or 1-phenyl-2-bromoethene, is a chemical compound with the molecular formula C9H9Br. It is a colorless to yellow liquid with a strong, sweet odor that is used in the production of various polymers and plastics such as polystyrene, synthetic rubber, and latex. It is also used as a precursor for the synthesis of other organic compounds and as a chemical intermediate in the manufacturing of adhesives, coatings, and resins. Additionally, (1-Bromomethyl-vinyl)-benzene is also used in the production of styrene-butadiene rubber and as a stabilizer for PVC (polyvinyl chloride) resins. However, it is important to handle this compound with caution as it is considered to be a hazardous chemical with potential health and environmental risks.

InChI:InChI=1/C9H9Br/c1-8(7-10)9-5-3-2-4-6-9/h2-6H,1,7H2

Upstream product

• 36043-44-4 (1,2-dibromopropan-2-yl)benzene 
• 98-82-8 Isopropylbenzene 
• 98-83-9 isopropenylbenzene 
• 4432-63-7 2-phenylacrolein 
• 122-78-1 phenylacetaldehyde 
• 2439-85-2 N-bromophthalimide 
• 98-86-2 acetophenone 
• 108-86-1 bromobenzene 
• 91083-18-0 (η5-C5H5)Ru(η3-2-phenylallyl)Br2 
• 3575-19-7 2-bromo-2-phenylpropane 
• 31778-29-7 1-bromo-2-phenylpropan-2-ol 
• 6006-81-1 3-hydroxy-2-phenylpropene 
• 437709-29-0 1-phenylcyclopropyl methanesulfonate 
• 70-11-1 α-bromoacetophenone 

Downstream Products

• 36963-72-1 (3-phenoxyprop-1-en-2-yl)benzene 
• 6006-81-1 3-hydroxy-2-phenylpropene 
• 7399-52-2 hexa-1,5-dien-2-ylbenzene 
• 112422-91-0 2-phenyl-2-propen-1-ol 3,5-dinitrobenzoate 
• 98525-71-4 ethyl 3-oxo-6-phenyl-6-heptenoate 
• 58567-50-3 N-[2-(phenyl)prop-2-en-1-yl]-N-(p-toluenesulfonyl)amide 
• 38279-94-6 2,5-diphenyl-4,4-bis(ethoxycarbonyl)-1-pentene 
• 63779-63-5 hexa-1,5-diene-2,4-diyldibenzene 
• 149097-99-4 (E)-1,5-diphenyl-1,5-hexadiene 
• 172980-72-2 methyl 4-oxo-2-(2-phenyl-2-propenyl)pentanoate ethylene ketal 
• 51875-99-1 dimethyl 2-phenylallylphosphonate 
• 197155-31-0 allyl-2-(2-phenyl-allyl)-malonic acid diethyl ester 
• 16606-47-6 2,4-diphenylbut-1-ene 
• 123078-75-1 (3-(allyloxy)prop-1-en-2-yl)benzene 

Relevant articles and documents

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Site-Selective Itaconation of Complex Peptides by Photoredox Catalysis

Site-selective peptide functionalization provides a straightforward and cost-effective access to diversify peptides for biological studies. Among many existing non-invasive peptide conjugations methodologies, photoredox catalysis has emerged as one of the powerful approaches for site-specific manipulation on native peptides. Herein, we report a highly N-termini-specific method to rapidly access itaconated peptides and their derivatives through a combination of transamination and photoredox conditions. This strategy exploits the facile reactivity of peptidyl-dihydropyridine in the complex peptide settings, complementing existing approaches for bioconjugations with excellent selectivity under mild conditions. Distinct from conventional methods, this method utilizes the highly reactive carbamoyl radical derived from a peptidyl-dihydropyridine. In addition, this itaconated peptide can be further functionalized as a Michael acceptor to access the corresponding peptide-protein conjugate.

Facile NBS/DMSO mediated dibromination of olefins including selected natural products and glycals

A highly chemo- and diastereoselective vic-dibromination of olefins has been developed. The process employs a readily available N-Bromosuccinimide (NBS)/DMSO reagent system as a bromine source. High substrate scope, simple reaction conditions, application to natural products and glycals makes the process very attractive. Graphical abstract: A highly chemo- and diastereoselective vic-dibromination of olefins has been developed. The process employs a readily available N-Bromosuccinimide (NBS)/DMSO reagent system as a bromine source. High substrate scope, simple reaction conditions, application to natural products and glycals makes the process very attractive. [Figure not available: see fulltext.].

The cascade coupling/iodoaminocyclization reaction of trifluoroacetimidoyl chlorides and allylamines: metal-free access to 2-trifluoromethyl-imidazolines

A metal-free cascade coupling/iodoaminocyclization reaction for the rapid assembly of 2-trifluoromethyl-imidazolines has been disclosed. The transformation applies readily accessible trifluoroacetimidoyl chlorides, allylamines andN-iodosuccinimides as the starting substrates, achieving an efficient and straightforward pathway to construct diverse imidazoline derivatives. Excellent efficiency of the reaction is observed (higher than 90% isolated yield for half of the examples), and the obtained imidazoline products bearing a pendent iodomethyl group could be easily transformed into other synthetically valuable compounds.