315179-98-7Relevant articles and documents
Photochromic, organogelating and self-sorting behaviour of di-(dithienylethene) derivatives
Zheng, Kun,Wang, Huaizhen,Chow, Hak-Fun
supporting information, p. 3285 - 3291 (2019/03/26)
A series of di-(dithienylethene) (DTE) tetraamides 4 diDTE-X-NHR was synthesized and characterized. Their organogelation property could be rationally optimized by controlling the extent of intramolecular vs. intermolecular hydrogen bonding and also by tuning the extent of side chain interdigitation. Among these compounds, diDTE-Dec-NHDodec4e showed excellent gelation properties with minimum gelation concentration (MGC) values ≤10 mg mL-1 in a wide variety of aromatic solvents. Upon UV (313 nm) irradiation, 32% of the DTE functionality in 4e underwent photocyclization accompanied with a photochromic change and a substantial weakening of the gel network structure. The pure doubly-cyclized isomer 4e-cc was separated and found to be a very weak organogelator (MGC ～25 mg mL-1) in a limited number of aromatic solvents. More interestingly, self-sorting of 4e and 4e-cc was observed in a 1:1 mixture of 4e and 4e-cc freeze-dried gel sample, indicating a high degree of non-self discrimination was present in the mixed gel of these two structurally similar isomers. The results demonstrated that such di-DTE derivatives are photochromic materials with interesting organogelating and self-sorting properties.
Synthesis of 6H-indolo[2,3-b][1,6]naphthyridines and related compounds as the 5-aza analogues of ellipticine alkaloids
Zhang,Shi,Zhang,Wang
, p. 7977 - 7983 (2007/10/03)
Treatment of 2-(1-alkynyl)phenyl isocyanates 6 with the iminophosphorane 14 produced in situ the benzoenynyl carbodiimides 15. Thermolysis of 15 under refluxing p-xylene furnished the 6H-indolo[2,3-b][1,6]naphthyridines 5, which could be regarded as the 5-aza analogues of ellipticine alkaloids. Similarly, condensation of 6 with the iminophosphorane 20 led to the formation of the 6H-indolo[2,3-b][1,5]naphthyridines 25 as the major isomer and the 10H-indolo[2,3-b][1,7]naphthyridines 26 as the minor isomer. The indolonaphthyridines 32, 33, and 34 having a methoxyl substituent were likewise synthesized. Treatment of the diisocyanate 43 with 2 equiv of the iminophosphorane 7 furnished 45 having two indoloquinoline units incorporated in a seven-fused-ring system.
