31591-08-9 Usage
Uses
Used in Research and Development:
N,N-DIMETHYL-D6-ACETAMIDE is used as a research compound for various applications in the scientific community. Its deuterated nature allows researchers to study the behavior and properties of molecules in a more controlled and precise manner, which is particularly useful in fields such as chemistry, biochemistry, and materials science.
Used in Chemical Reactions:
In the field of chemistry, N,N-DIMETHYL-D6-ACETAMIDE serves as a solvent or reagent in various chemical reactions. Its isotopically labeled nature enables chemists to track the progress of reactions and better understand the mechanisms involved, leading to improved reaction conditions and more efficient processes.
Used in Biochemical Studies:
In biochemistry, N,N-DIMETHYL-D6-ACETAMIDE is employed in studies involving the interaction of molecules with biological systems. The deuterium labeling allows for the investigation of enzyme kinetics, protein folding, and other biochemical processes, providing valuable insights into the underlying mechanisms and potential applications in drug development and therapeutics.
Used in Materials Science:
N,N-DIMETHYL-D6-ACETAMIDE is also utilized in materials science for the development and characterization of new materials. Its isotopically labeled properties can help researchers gain a deeper understanding of the structure, properties, and behavior of materials at the molecular level, which is crucial for the advancement of materials with specific applications, such as in electronics, energy storage, and nanotechnology.
Check Digit Verification of cas no
The CAS Registry Mumber 31591-08-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,1,5,9 and 1 respectively; the second part has 2 digits, 0 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 31591-08:
(7*3)+(6*1)+(5*5)+(4*9)+(3*1)+(2*0)+(1*8)=99
99 % 10 = 9
So 31591-08-9 is a valid CAS Registry Number.
31591-08-9Relevant academic research and scientific papers
Reactions of the cumyloxyl and benzyloxyl radicals with tertiary amides. hydrogen abstraction selectivity and the role of specific substrate-radical hydrogen bonding
Salamone, Michela,Milan, Michela,Dilabio, Gino A.,Bietti, Massimo
, p. 5909 - 5917 (2013/07/26)
A time-resolved kinetic study in acetonitrile and a theoretical investigation of hydrogen abstraction reactions from N,N-dimethylformamide (DMF) and N,N-dimethylacetamide (DMA) by the cumyloxyl (CumO?) and benzyloxyl (BnO?) radicals was carried out. CumO ? reacts with both substrates by direct hydrogen abstraction. With DMF, abstraction occurs from the formyl and N-methyl C-H bonds, with the formyl being the preferred abstraction site, as indicated by the measured k H/kD ratios and by theory. With DMA, abstraction preferentially occurs from the N-methyl groups, whereas abstraction from the acetyl group represents a minor pathway, in line with the computed C-H BDEs and the kH/kD ratios. The reactions of BnO? with both substrates were best described by the rate-limiting formation of hydrogen-bonded prereaction complexes between the BnO? α-C-H and the amide oxygen, followed by intramolecular hydrogen abstraction. This mechanism is consistent with the very large increases in reactivity measured on going from CumO? to BnO? and with the observation of kH/kD ratios close to unity in the reactions of BnO?. Our modeling supports the different mechanisms proposed for the reactions of CumO? and BnO ? and the importance of specific substrate/radical hydrogen bond interactions, moreover providing information on the hydrogen abstraction selectivity.
