31599-52-7Relevant academic research and scientific papers
Conversion of aryl iodides into aryliodine(III) dichlorides by an oxidative halogenation strategy using 30% aqueous hydrogen peroxide in fluorinated alcohol
Podgorsek, Ajda,Iskra, Jernej
experimental part, p. 2857 - 2871 (2010/06/20)
Oxidative chlorination with HCl/H2O2 in 1,1,1-trifluoroethanol was used to transform aryl iodides into aryliodine(III) dihalides. In this instance 1,1,1-trifluoroethanol is not only the reaction medium, but is also an activator of hy
A solvent-free synthesis of (dichloroiodo)arenes from iodoarenes
Zielinska, Agnieszka,Skulski, Lech
, p. 1087 - 1089 (2007/10/03)
An efficient solid-state oxidation of iodoarenes, ArI, is described using the urea-hydrogen peroxide adduct (UHP), a stable, inexpensive, and easily handled oxidant. The reactions were complete in 15min at 85°C. The melts thus obtained were reacted with e
One-pot procedures for preparing (dichloroiodo)arenes from arenes and diiodine, with chromium(VI) oxide as the oxidant
Obeid, Nicolas,Skulski, Lech
, p. 869 - 874 (2007/10/03)
Ten representative (dichloroiodo)arenes, ArICl2, were prepared from the corresponding arenes and diiodine in variable anhydrous mixtures, ArH/I2/CrO3/AcOH/Ac2O/conc. H 2SO4, followed by the
Biphasic chlorination of iodoarenes to (dichloroiodo)arenes
Krassowska-?wiebocka, Barbara,Prokopienko, Grazyna,Skulski, Lech
, p. 1409 - 1410 (2007/10/03)
A two-phase (CCl4/conc. hydrochloric acid) chlorination of some iodoarenes to the corresponding (dichloroiodo)arenes, prepared in 50-98% crude yields, is reported. Dichlorine is produced in the aqueous phase as follows: KClO3 (solid) + 6 HCl (conc. aq.) → ↑3Cl2 + KCl + 3H2O.
