31600-88-1

Basic information

• Product Name: Lithium, (3-methoxyphenyl)-
• CAS NO: 31600-88-1
• Molecular Formula: C7H7LiO
• Molecular Weight: 114.073
• Mol File: 31600-88-1.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Lithium, (3-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Lithium, (3-methoxyphenyl)-(31600-88-1)
• EPA Substance Registry System: Lithium, (3-methoxyphenyl)-(31600-88-1)

Safety Data

• Hazardous Substances Data: 31600-88-1(Hazardous Substances Data)

Upstream product

• 766-85-8 3-methoxy-1-iodobenzene 
• 591-51-5 phenyllithium 
• 2398-37-0 3-methoxyphenyl bromide 

Downstream Products

• 2132-80-1 4,4'-Dimethoxybiphenyl 
• 6161-50-8 3,3'-dimethoxybiphenyl 
• 84591-12-8 1-methoxy-3-(4-methoxyphenyl)benzene 
• 605-39-0 2,2'-dimethyl-1,1'-biphenyl 
• 135227-03-1 3-methoxy-2'-methyl-1,1'-biphenyl 
• 120413-66-3 4-Hydroxy-4-(3-methoxy-phenyl)-4H-naphthalen-1-one 
• 14318-66-2 3-methoxy-N-methylaniline 
• 31084-58-9 N-tert-Butyl-3-methoxyaniline 
• 445039-90-7 (3-methoxyphenyl)(6-(4-methylthiophenyl)(2H-benzo[d]1,3-dioxolan-5-yl))methan-1-ol 
• 15547-89-4 2-(3-methoxyphenyl)cyclohexanone 
• 766-85-8 3-methoxy-1-iodobenzene 
• 1493-23-8 (4-fluorophenyl)lithium 
• 1189783-24-1 6-chloro-2-(3-methoxyphenyl)-1H-indole 
• 1609637-58-2 (±)-4-(3-methoxyphenyl)-1-methyl-5-phenyl-3,4-dihydropyrimidine-2(1H)-thione 

Relevant articles and documents

Synthesis of Benzosiloles by Intramolecular anti-Hydroarylation via ortho-C-H Activation of Aryloxyethynyl Silanes

Straightforward synthesis of benzosiloles was achieved by the invention of Pd/acid-catalyzed intramolecular anti-hydroarylation of aryloxyethynyl(aryl)silanes via ortho-C-H bond activation. The aryloxy group bound to the ethynyl carbon is the key factor for this transformation.

Regioselective synthesis of novel 4,5-diaryl functionalized 3,4-dihydropyrimidine-2(1H)-thiones via a non-Biginelli-type approach and evaluation of their in vitro anticancer activity

An easy and novel approach to synthesize 4,5-diaryl functionalized 3,4-dihydropyrimidine-2(1H)-thiones via addition of aryllithiums to 5-aryl substituted pyrimidine-2(1H)-thiones, which could be regarded as a method complementary to the most widely used Biginelli-type synthesis, is described. In the reaction of aryllithiums with N-(Me)Bn substituted pyrimidine-2(1H)-thiones a high degree of regioselectivity of addition, leading to 4-aryl adducts, was achieved. Selected compounds tested for their in vitro anticancer activity against four human cancer cell lines showed the greatest activity against breast cancer (MCF7). 1-Benzyl-4-(3-hydroxyphenyl)-5-phenyl substituted 3,4-dihydropyrimidine-2(1H)-thione (10g) exhibiting 10-fold more potent activity than the best known monastrol (MON) stands as a promising candidate for further scaffold and asymmetric synthesis. the Partner Organisations 2014.

The Reactions of Optically Pure Menthyloxymethylphenylphosphine-Borane with Organolithium Reagents

The reactions of (Rp)-menthyloxymethylphenylphosphine-borane with several organolithium reagents are described.Less sterically hindered reagents such as m-anisyllithium and p-anisyllithium react with the phospine-borane to afford the correspond