316384-29-9Relevant academic research and scientific papers
Gold(I)-catalyzed intramolecular [4+2] cycloadditions of arylalkynes or 1,3-enynes with alkenes: Scope and mechanism
Nieto-Oberhuber, Cristina,Perez-Galan, Patricia,Herrero-Gomez, Elena,Lauterbach, Thorsten,Rodriguez, Cristina,Lopez, Salome,Bour, Christophe,Rosellon, Antonio,Cardenas, Diego J.,Echavarren, Antonio M.
, p. 269 - 279 (2008/09/20)
The cyclizations of enynes substituted at the alkyne gives products of formal [4+2] cyclization with Au(I) catalysts. 1,8-Dien-3-ynes cyclize by a 5-exo-dig pathway to form hydrindanes. 1,6-Enynes with an aryl ring at the alkyne give 2,3,9,9a-tetrahydro-1
