3164-74-7

Basic information

• Product Name: 1-(nitromethyl)cyclohexyl acetate
• CAS NO: 3164-74-7
• Molecular Formula: C₉H₁₅NO₄
• Molecular Weight: 201.2197
• Mol File: 3164-74-7.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 291°C at 760 mmHg
• Flash Point: 123.5°C
• Density: 1.15g/cm³
• Vapor Pressure: 0.00201mmHg at 25°C
• Refractive Index: 1.478
• CAS DataBase Reference: 1-(nitromethyl)cyclohexyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(nitromethyl)cyclohexyl acetate(3164-74-7)
• EPA Substance Registry System: 1-(nitromethyl)cyclohexyl acetate(3164-74-7)

Safety Data

• Hazardous Substances Data: 3164-74-7(Hazardous Substances Data)

Usage

General Description

1-(nitromethyl)cyclohexyl acetate is a chemical compound with the molecular formula C9H15NO4. It is a nitro compound and has a cyclohexyl group and an acetate group. 1-(nitromethyl)cyclohexyl acetate is commonly used in the synthesis of organic compounds and pharmaceuticals. It is also used as a solvent and a reagent in various chemical reactions. The nitro group in the molecule makes it reactive and versatile for use in organic synthesis. It is important to handle this chemical with care as it can be hazardous if not handled properly.

Upstream product

• 463-51-4 Ketene 
• 3164-73-6 1-nitromethylcyclohexanol 
• 108-94-1 cyclohexanone 
• 108-24-7 acetic anhydride 

Downstream Products

• 27861-39-8 (nitromethylene)cyclohexane 
• 5330-61-0 1-nitromethyl-cyclohexene 
• 32379-37-6 1-Acetoxy-cyclohexylcyanid 
• 128165-05-9 1-(nitromethyl)-1-(trimethylsilyl)cyclohexane 
• 92432-05-8 C-(1-benzylsulphanyl-cyclohexyl)-methylamine 
• 99063-44-2 2-cyclohex-1-enyl-2-nitro-propane-1,3-diol 
• 94027-00-6 (E)-1-cyclohex-1-enyl-2-(4-methoxy-phenyl)-1-nitro-ethene 
• 890-75-5 (E)-2-(4-chloro-phenyl)-1-cyclohex-1-enyl-1-nitro-ethene 
• 1192-37-6 methylenecyclohexane 
• 128165-06-0 1-(aminomethyl)-1-(trimethylsilyl)cyclohexane 

Relevant articles and documents

2 plus 2.

The reactions of AcONO//2 with the cyclic olefins cyclopentene, cyclohexane, cis-cyclooctene, methylenecyclobutane, and norbornene have been investigated or, in some cases, reinvestigated. Although many products are formed, material balances in the order

1,3-Difunctionalization of β-alkyl nitroalkenes via combination of Lewis base catalysis and radical oxidation

Upon treatment with a Lewis base catalyst, β-alkyl-substituted nitroalkenes could be readily converted into allylic nitro compounds. Examples of either C-1 or C-3 functionalization methods have been reported through nitro-elimination, giving alkene products. In this work, successful 1,3-difunctionalization was achieved through a synergetic Lewis base catalysis and TBHP radical oxidation, giving vinylic alkoxyamines in good to excellent yields. This work further extended the general synthetic application of β-alkyl nitroalkenes.