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4-CHLORO-O-TOLUIDINE HYDROCHLORIDE is a white crystalline solid that is toxic by skin absorption and inhalation (dust). It belongs to the chloromethylanilines group, which are colorless or white crystalline solids or liquids, some of which have a mild fishy odor.

3165-93-3

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3165-93-3 Usage

Uses

Used in Textile Industry:
4-CHLORO-O-TOLUIDINE HYDROCHLORIDE is used as an intermediate in the manufacturing of azo dyes for cotton, silk, acetate, and nylon. It plays a crucial role in producing vibrant and long-lasting colors in these fabrics.
Used in Pigment Production:
In the pigment industry, 4-CHLORO-O-TOLUIDINE HYDROCHLORIDE is used as an intermediate for the production of dyes such as C.I. 12800, pigment red 7, and pigment yellow 49. These pigments are essential for creating a wide range of colors in various applications.
Used in Pesticide Manufacturing:
4-CHLORO-O-TOLUIDINE HYDROCHLORIDE has been used since the 1960s as an intermediate in the manufacture of the pesticide chlordimeform, which acts as an insecticide and acaricide. However, it is believed that chlordimeform is no longer produced or used worldwide.

Air & Water Reactions

4-CHLORO-O-TOLUIDINE HYDROCHLORIDE may be sensitive to prolonged exposure to air and light. Water soluble.

Reactivity Profile

Incompatible with acids, acid chlorides, acid anhydrides, chloroformates and strong oxidizing agents. .

Hazard

Toxic by ingestion, inhalation, and skin absorption.

Health Hazard

TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.

Safety Profile

Confirmed carcinogen with experimental carcinogenic data. Moderately toxic by intraperitoneal route. When heated to decomposition it emits toxic fumes of NOx and Cl-. See also other chloro toluidine entries.

Potential Exposure

Most of the isomers are used in dyestuff manufacture. The 3-chloro-para isomer is used to kill birds. It is marketed as pelleted bait for control of bird populations.

Carcinogenicity

p-Chloro-o-toluidine and its hydrochloride salt are reasonably anticipated to be human carcinogens based on limited evidence of carcinogenicity from studies in humans and evidence of carcinogenicity from studies in experimental animals.

Shipping

UN2239 Chlorotoluidines, solid, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3429 Chlorotoluidines, liquid, Hazard Class: 6.1; Labels: 6.1- Poisonous materials

Incompatibilities

Incompatible with oxidizers, strong acids; chloroformates, and acid anhydrides, isocyanates, aldehydes forming fire and explosive hazards.

Check Digit Verification of cas no

The CAS Registry Mumber 3165-93-3 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 3,1,6 and 5 respectively; the second part has 2 digits, 9 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 3165-93:
(6*3)+(5*1)+(4*6)+(3*5)+(2*9)+(1*3)=83
83 % 10 = 3
So 3165-93-3 is a valid CAS Registry Number.
InChI:InChI=1/C7H8ClN.ClH/c1-5-4-6(8)2-3-7(5)9;/h2-4H,9H2,1H3;1H

3165-93-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name 4-chloro-2-methylaniline,hydrochloride

1.2 Other means of identification

Product number -
Other names Diazo Fast Red TR

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:3165-93-3 SDS

3165-93-3Relevant academic research and scientific papers

Liquid-crystalline ionic liquids

Bowlas, Christopher J.,Bruce, Duncan W.,Seddon, Kenneth R.

, p. 1625 - 1626 (2007/10/03)

Low-melting point salts, the basis of industrially relevant ionic liquids, exhibit smectic A mesophases over extended temperature ranges.

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