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3165-93-3

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CAS No.: 3165-93-3
Name: 4-CHLORO-O-TOLUIDINE HYDROCHLORIDE
Article Data: 3
Molecular Structure:
Molecular Structure of 3165-93-3 (4-CHLORO-O-TOLUIDINE HYDROCHLORIDE)
Formula: C7H8 Cl N . Cl H
Molecular Weight: 178.061
Synonyms: Benzenamine,4-chloro-2-methyl-, hydrochloride (9CI); o-Toluidine, 4-chloro-, hydrochloride(8CI); 2-Methyl-4-chloroaniline hydrochloride; 4-Chloro-2-methylanilinehydrochloride; 4-Chloro-2-methylbenzenamine hydrochloride; 4-Chloro-o-toluidinehydrochloride; Azogene Fast Red TR; C.I. 37085; Devol Red K; Devol Red TR;Neutrosel Red TRVA; p-Chloro-o-toluidine hydrochloride
Density: 1.18g/cm3
Melting Point: -93.6°C
Boiling Point: 242.8°Cat760mmHg
Flash Point: 99.4°C
Appearance: colourless gas
Hazard Symbols: Xi
Safety: Confirmed carcinogen with experimental carcinogenic data. Moderately toxic by intraperitoneal route. When heated to decomposition it emits toxic fumes of NOx and Cl−. See also other chloro toluidine entries.
PSA: 26.02000
LogP: 3.61380
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Chemistry

IUPAC Name:  4-Chloro-2-methylaniline hydrochloride
Synonyms:  4-Chloro-2-methylaniline hydrochloride (1:1) ; 4-Chloro-2-methylbenzenamine hydrochloride ; 4-Chloro-2-toluidine hydrochloride ; 4-Chloro-6-methylaniline hydrochloride ; 4-Chloro-o-toluidine hydrochloride ; 4-Chloro-o-toluidine hydrochloride ; Asymmetric meta-chloro-ortho-toluidine hydrochloride ; Benzenamine, 4-chloro-2-methyl-, hydrochloride
The Molecular Formula of  4-Chloro-2-toluidine hydrochloride (CAS NO.3165-93-3):C7H9Cl2N
The Molecular Weight of  4-Chloro-2-toluidine hydrochloride (CAS NO.3165-93-3):178.059060g/mol
The Molecular Structure of  4-Chloro-2-toluidine hydrochloride (CAS NO.3165-93-3):
Appearance: white crystalline solid
Flash Point: 99.4 °C
Enthalpy of Vaporization: 47.97 kJ/mol
Boiling Point: 242.8 °C at 760 mmHg
Vapour Pressure: 0.0334 mmHg at 25°C

Toxicity Data With Reference

1.    

ipr-rat LD50:560 mg/kg

     NCIBR*    Progress Report for Contract No. NIH-NCI-E-68-1311, Submitted to the National Cancer Institute by Bio-Research Consultants, Inc. (9 Commercial Ave., Cambridge, MA 02141) NCI-E-68-1311 ,1973.
2.    

ipr-mus LD50:680 mg/kg

     NCIBR*    Progress Report for Contract No. NIH-NCI-E-68-1311, Submitted to the National Cancer Institute by Bio-Research Consultants, Inc. (9 Commercial Ave., Cambridge, MA 02141) NCI-E-68-1311 ,1973.

Consensus Reports

NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2A IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 48 , 1990,p. 123.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Inadequate Evidence, Human Inadequate Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 16 , 1978,p. 277.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . NCI Carcinogenesis Bioassay (feed); Clear Evidence: mouse; No Evidence: rat NCITR*    National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD 20014) No. NCI-CG-TR-165 ,1979. . Reported in EPA TSCA Inventory.

Safety Profile

Confirmed carcinogen with experimental carcinogenic data. Moderately toxic by intraperitoneal route. When heated to decomposition it emits toxic fumes of NOx and Cl−. See also other chloro toluidine entries.
RIDADR: 1579
RTECS: XU5250000
HazardClass: 6.1(b)
PackingGroup: III

Standards and Recommendations

DOT Classification:  6.1; Label: KEEP AWAY FROM FOOD