31650-07-4

Upstream product

• 673-32-5 1-Phenylprop-1-yne 
• 75-77-4 chloro-trimethyl-silane 
• 50874-13-0 1-methoxy-1-phenylpropyne 
• 1066-54-2 trimethylsilylacetylene 
• 286387-62-0 (cyclohepta-2,4,6-trien-1-ylethynyl)trimethylsilane 
• 13829-77-1 3-(trimethylsilyl)-1-phenyl-2-propyn-1-one 
• 19319-11-0 (Z)-1-phenyl-2-(trimethylsilyl)ethylene 
• 19372-00-0 1-(trimethylsilyl)-2-phenylethene 
• 118804-16-3 1-methoxy-4,4-dimethyl-1-phenyl-4-sila-2-pentyne 
• 38718-81-9 (3,3-Bis-trimethylsilanyl-1-trimethylsilanyloxy-propa-1,2-dienyl)-benzene 

Relevant academic research and scientific papers

Stereocontrol in ene-dimerisation and trimerisation of 1-trimethylsilyl-3- phenylcyclopropene

1-Trimethylsilyl-3-phenylcyclopropene undergoes a highly stereocontrolled ene-reaction to give a dimer and further reaction leads to one or more trimers derived through two ene-reactions.

Rh(II)-Catalyzed Alkynylcyclopropanation of Alkenes by Decarbenation of Alkynylcycloheptatrienes

Alkynylcyclopropanes have found promising applications in both organic synthesis and medicinal chemistry but remain rather underexplored due to the challenges associated with their preparation. We describe a convenient two-step methodology for the alkynyl

Stereo- and regiocontrol in ene-dimerisation and trimerisation of 1-trimethylsilyl-3-phenylcyclopropene

1-Trimethylsilyl-3-phenylcyclopropene and its 2D-analog undergo a highly stereocontrolled ene-reaction to give a single dimer. Further reaction leads to one or more trimers derived through two ene-reactions. The dimer formed easily undergoes cycloaddition

ALKINE UND CUMULENE-XX. TRIMETHYLSILYLALLENE DURCH RETRO-EN-SPALTUNG VON TRIMETHYLSILYLPROPARGYLETHERN

The trimethylsilylallenes 3a-f are obtained in excellent yields when thepropargylic precursors 2a-f are subjected to low pressure flow pyrolysis at ca. 620 deg C.