31673-32-2Relevant academic research and scientific papers
Enantioselective total synthesis of sagittacin e and related natural products
Abe, Hideki,Fujimaki, Mitsuru,Nakagawa, Eri,Kobayashi, Toyoharu,Ito, Hisanaka
, p. 6165 - 6168 (2018)
The first enantioselective total synthesis of eremophilane-type sesquiterpenoids, sagittacin E and related natural products, was achieved. This synthesis features an asymmetric desymmetrization by Shi asymmetric epoxidation, intramolecular aldol-type cyclization, allylic oxidation of a 1,4-diene compound, and stereoselective epoxidation.
