31733-80-9Relevant academic research and scientific papers
Hypervalent iodine(III)-mediated oxidative dearomatizing cyclization of arylamines
Jin, Cong-Yang,Du, Ji-Yuan,Zeng, Chao,Zhao, Xian-He,Cao, Ye-Xing,Zhang, Xiang-Zhi,Lu, Xin-Yun,Fan, Chun-An
supporting information, p. 2437 - 2444 (2014/09/17)
An oxidative dearomatizing cyclization of arylamines promoted by iodobenzene bis(trifluoroacetate) [PhI(CF3CO2) 2] has been explored, leading to a novel synthetic approach to functionalized spirocyclic building blocks containing the structurally unique dieniminium moiety. This unprecedented methodology, featuring oxidative dearomatization and carbon-carbon bond-forming cyclization, to some extent, not only expands the synthetic potential of hypervalent iodine chemistry, but also enriches the oxidation chemistry of arylamines.
