31735-56-5Relevant academic research and scientific papers
Palladium-catalyzed hydrophosphonylation of alkenes with dialkyl H-phosphonates
Candy, Mathieu,Rousseaux, Sophie A. L.,Sanroman, Alberto Cirugeda,Szymczyk, Monika,Kafarski, Pawel,Leclerc, Eric,Vrancken, Emmanuel,Campagne, Jean-Marc
, p. 2703 - 2708 (2014)
The palladium-catalyzed hydrophosphonylation of alkenes with previously unreactive acyclic dialkyl H-phosphonates has been developed. A catalyst system based on palladium/DavePhos or palladium/SPhos enables the transformation of various alkenes to phospho
Bismuth(III)-Catalyzed Sequential Enamine-Imine Tautomerism/2-Aza-Cope Rearrangement of Stable β-Enaminophosphonates: One-Pot Synthesis of β-Aminophosphonates
Jin, Ming,Yin, Shi-Fu,Yang, Shang-Dong
supporting information, p. 2811 - 2815 (2020/03/30)
A novel catalytic tautomeric transformation of a β-enaminophosphoryl and 2-aza-Cope rearrangement sequence has been successfully applied to the one-pot synthesis of β-aminophosphonates with high efficiency and good tolerance. In this tandem reaction, Bi(OTf)3 exhibits unique activities and promotes both of enamine-imine tautomerism and 2-aza-Cope rearrangement.
